溴代炔酮与 AgSCF 的亲核三氟甲基硫代化反应：形成 C(sp)-SCF 键的炔基三氟甲基硫醚。
Nucleophilic trifluoromethylthiolation of bromoalkynones with AgSCF: C(sp)-SCF bond formation towards ynonyl trifluoromethyl sulfides.
机构信息
Key Laboratory of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China.
出版信息
Org Biomol Chem. 2018 Mar 7;16(10):1646-1650. doi: 10.1039/c8ob00007g.
PMID:29465727
Abstract
An AgSCF mediated nucleophilic trifluoromethylthiolation reaction for C(sp)-SCF bond formation is reported. This nucleophilic trifluoromethylthiolation reaction of bromoalkynones afforded various useful ynonyl trifluoromethyl sulfides in high yields. Interestingly, the over-addition of AgSCF is avoided in our approach.
摘要
本文报道了 AgSCF 介导的亲核三氟甲基硫代反应，用于 C(sp)-SCF 键的形成。该亲核三氟甲基硫代反应可使溴代炔酮高收率地得到各种有用的炔基三氟甲基硫化物。有趣的是，我们的方法避免了 AgSCF 的过度加成。
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