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一步法制备用于定向水分传输的多尺度、相互连接的分级纤维膜。

One-step fabrication of multi-scaled, inter-connected hierarchical fibrous membranes for directional moisture transport.

作者信息

Ahmed Babar Aijaz, Zhao Xinglei, Wang Xianfeng, Yu Jianyong, Ding Bin

机构信息

State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China; Innovation Center for Textile Science and Technology, Donghua University, Shanghai 200051, China; Textile Engineering Department, Mehran University of Engineering & Technology, Jamshoro 76060, Pakistan.

Key Laboratory of Textile Science & Technology, Ministry of Education, College of Textiles, Donghua University, Shanghai 201620, China; Innovation Center for Textile Science and Technology, Donghua University, Shanghai 200051, China.

出版信息

J Colloid Interface Sci. 2020 Oct 1;577:207-216. doi: 10.1016/j.jcis.2020.05.062. Epub 2020 May 21.

Abstract

HYPOTHESIS

Functional textiles engineered for maintaining body comfort by fast sweat release using the directional moisture transport concept are in high demand. However, designing these functional textiles remains a critical job and generally requires multi-step complex fabrication routes. In this regard, developing one-step strategy to fabricate multi-scaled, inter-connected nonwoven-nanofiber/nets hierarchical fibrous composite membranes with asymmetric wettability for enhanced directional moisture transport would be a very fruitful approach.

EXPERIMENT

Composite membranes were fabricated by the rational combination of commercial polyethylene terephthalate nonwoven (CNW) as hydrophobic layer, and polyamide and silver nanoparticles (PA-Ag) nanofiber/nets as hydrophilic layer via one-step electrospinning process.

FINDINGS

The resultant CNW/PA-Ag nanofiber/net composite membranes were carefully investigated for water vapor transport, moisture management performance, and antibacterial activity. The subsequent membranes not only exhibit exceptionally high one-way moisture transport index (1253%), considerably high water vapor transport rate (11.45 Kg md), and overall moisture management capacity (0.91), but also offer high resistance of 16.9 cm HO to prohibit the moisture drive in the opposite way, and considerable antibacterial activity against Escherichia coli and Staphylococcus aureus. The effective one-step fabrication of such fascinating directional moisture transport membranes with decent antibacterial activity opens a new intuition into the designing of novel functional materials for rapid sweat release and personal drying applications.

摘要

假设

利用定向水分传输概念设计的、通过快速排汗来保持身体舒适的功能性纺织品需求旺盛。然而,设计这些功能性纺织品仍然是一项关键工作,通常需要多步骤的复杂制造工艺。在这方面,开发一种一步法策略来制造具有不对称润湿性的多尺度、相互连接的非织造纳米纤维/网分层纤维复合膜,以增强定向水分传输,将是一种非常有效的方法。

实验

通过一步静电纺丝工艺,将商用聚对苯二甲酸乙二酯非织造布(CNW)作为疏水层,聚酰胺和银纳米颗粒(PA-Ag)纳米纤维/网作为亲水层进行合理组合,制备复合膜。

发现

对所得的CNW/PA-Ag纳米纤维/网复合膜进行了水蒸气传输、水分管理性能和抗菌活性的详细研究。后续的膜不仅表现出极高的单向水分传输指数(1253%)、相当高的水蒸气传输速率(11.45 Kg m⁻² d⁻¹)和整体水分管理能力(0.91),而且还具有16.9 cm H₂O的高阻力,以防止水分反向驱动,并且对大肠杆菌和金黄色葡萄球菌具有相当的抗菌活性。这种具有良好抗菌活性的迷人定向水分传输膜的有效一步制造,为设计用于快速排汗和个人干燥应用的新型功能材料开辟了新的思路。

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