Litasov Konstantin D, Bekker Tatyana B, Sagatov Nursultan E, Gavryushkin Pavel N, Krinitsyn Pavel G, Kuper Konstantin E
Vereshchagin Institute for High Pressure Physics RAS, Troitsk, Moscow, 108840, Russia.
Sobolev Institute of Geology and Mineralogy SB RAS, Novosibirsk, 630090, Russia.
Sci Rep. 2020 Jun 2;10(1):8956. doi: 10.1038/s41598-020-66039-0.
An orthorhombic modification of (Fe,Ni)P, allabogdanite, found in iron meteorites was considered to be thermodynamically stable at pressures above 8 GPa and temperatures of 1673 K according to the results of recent static high-pressure and high-temperature experiments. A hexagonal polymorphic modification of (Fe,Ni)P, barringerite, was considered to be stable at ambient conditions. Experimental investigation through the solid-state synthesis supported by ab initio calculations was carried out to clarify the stability fields of (Fe,Ni)P polymorphs. Both experimental and theoretical studies show that FeP-allabogdanite is a low-temperature phase stable at ambient conditions up to a temperature of at least 773 K and, therefore, is not necessarily associated with high pressures. This is consistent with the textural relationships of allabogdanite in iron meteorites.
根据最近的静态高压和高温实验结果,在铁陨石中发现的(铁,镍)磷正交变体——镍磷铁矿,被认为在压力高于8吉帕斯卡和温度为1673K时是热力学稳定的。(铁,镍)磷的六方多晶型变体——巴林杰矿,被认为在环境条件下是稳定的。通过从头算计算支持的固态合成进行了实验研究,以阐明(铁,镍)磷多晶型体的稳定场。实验和理论研究均表明,铁磷镍磷铁矿是一种低温相,在环境条件下直至至少773K的温度都是稳定的,因此不一定与高压相关。这与铁陨石中镍磷铁矿的结构关系是一致的。