由混合杂阴离子模板化的夹心型杂多铌酸盐。
Sandwich-Type Heteropolyniobate Templated by Mixed Heteroanions.
作者信息
Liang Zhijie, He Yuzan, Qiao Yuanyuan, Ma Pengtao, Niu Jingyang, Wang Jingping
机构信息
Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, Henan, People's Republic of China.
College of Textile and Clothing, Nantong University, Nantong 226019, Jiangsu, People's Republic of China.
出版信息
Inorg Chem. 2020 Jun 15;59(12):7895-7899. doi: 10.1021/acs.inorgchem.0c00312. Epub 2020 Jun 4.
A new organic-inorganic hybrid heteropolyoxoniobate, [{Cu(en)(HO)}{Cu(en)(HO)}{Cu(en)(HO)}][HSiTeNbO]·6HO (; en = ethanediamine), has been successfully synthesized by a conventional method. The compound was directed by pairs of [TeO]/[SiO] ions, generating two novel {TeNb} and {SiTeNb} subunits in situ owing to the mixed heteroanion. In addition, the solution behavior of compound was investigated.
一种新型的有机-无机杂化铌氧杂多酸盐，[{Cu(en)(HO)}{Cu(en)(HO)}{Cu(en)(HO)}][HSiTeNbO]·6HO（；en = 乙二胺），已通过传统方法成功合成。该化合物由[TeO]/[SiO]离子对导向，由于混合杂阴离子原位生成了两个新型的{TeNb}和{SiTeNb}亚基。此外，还研究了化合物的溶液行为。
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