金属有机框架材料的力量：可切换金属有机框架作为溶剂刺激致动器的潜力。
The force of MOFs: the potential of switchable metal-organic frameworks as solvent stimulated actuators.
作者信息
Freund Pascal, Senkovska Irena, Zheng Bin, Bon Volodymyr, Krause Beate, Maurin Guillaume, Kaskel Stefan
机构信息
Inorganic Chemistry I, Technische Universität Dresden, Bergstraße 66, 01062 Dresden, Germany.
出版信息
Chem Commun (Camb). 2020 Jul 11;56(54):7411-7414. doi: 10.1039/d0cc02505d. Epub 2020 Jun 4.
We evaluate experimentally the force exerted by flexible metal-organic frameworks through expansion for a representative model system, namely MIL-53(Al). The results obtained are compared with data collected from intrusion experiments while molecular simulations are performed to shed light on the re-opening of the guest-loaded structure. The critical impact of the transition stimulating medium on the magnitude of the expansion force is demonstrated.
我们通过膨胀对一个具有代表性的模型体系，即MIL-53(Al)，进行了实验评估柔性金属有机框架施加的力。将获得的结果与从侵入实验收集的数据进行比较，同时进行分子模拟以阐明客体负载结构的重新开放情况。证明了过渡刺激介质对膨胀力大小的关键影响。
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