Torubaev Yury V
N.S. Kurnakov Institute of General and Inorganic Chemistry of Russian Academy of Sciences (IGIC RAS), Moscow, Russian Federation.
Acta Crystallogr C Struct Chem. 2020 Jun 1;76(Pt 6):579-584. doi: 10.1107/S2053229620006166. Epub 2020 May 18.
Iodination of PhTeSe by molecular iodine is directed towards the Te atom and yields {diiodo[(phenyltellanyl)selanyl]-λ-tellanyl}benzene, PhTeSeTeIPh or CHISeTe. The molecule can be considered as a chimera of PhTeSeR, PhTeSeTePh and R'TeIPh fragments. The crystal structure features a complex interplay of the supramolecular synthons Te...π(Ph), Se...Te and I...Te, combining molecules into a three-dimensional framework. Their combination affords long-range supramolecular synthons which are fused in a way resembling the mythological chimera and could be defined as chimeric supramolecular synthons. The energies of the intermolecular interactions have also been calculated and analyzed.
分子碘对PhTeSe进行碘化反应时，反应指向碲（Te）原子，生成{二碘代[(苯基碲基)硒基]-λ-碲基}苯，即PhTeSeTeIPh或CHISeTe。该分子可被视为PhTeSeR、PhTeSeTePh和R'TeIPh片段的嵌合体。晶体结构具有超分子合成子Te...π(Ph)、Se...Te和I...Te之间复杂的相互作用，将分子组合成三维框架。它们的组合产生了远程超分子合成子，其融合方式类似于神话中的嵌合体，可被定义为嵌合超分子合成子。还对分子间相互作用的能量进行了计算和分析。
