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用于有机发光二极管的硼基高效纯蓝色热激活延迟荧光材料的最新进展

Recent Advancement in Boron-Based Efficient and Pure Blue Thermally Activated Delayed Fluorescence Materials for Organic Light-Emitting Diodes.

作者信息

Lee Hyuna, Karthik Durai, Lampande Raju, Ryu Jae Hong, Kwon Jang Hyuk

机构信息

Organic Optoelectronic Device Laboratory, Information Display Department, Kyung Hee University, Seoul, South Korea.

出版信息

Front Chem. 2020 May 19;8:373. doi: 10.3389/fchem.2020.00373. eCollection 2020.

DOI:10.3389/fchem.2020.00373
PMID:32509723
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7248410/
Abstract

In the last few years, electron-deficient materials have been actively researched for application in organic light-emitting diode (OLED) as dopant and electron-transporting materials. The boron-containing materials are interesting as they give good emissive properties in solid state with an electron-accepting character. Recently, many boron-containing materials are used as emissive materials for thermally activated delayed fluorescence (TADF) OLED applications. In this review, boron acceptor-based push-pull small molecules used for application in blue TADF OLEDs are reviewed, covering their different types of acceptor, molecular design, structure-property relation, material properties, and device properties. Also, the importance of boron acceptors to address the key issue of blue TADF OLEDs is discussed.

摘要

在过去几年中,缺电子材料作为掺杂剂和电子传输材料在有机发光二极管(OLED)中的应用受到了积极研究。含硼材料因其在固态下具有良好的发射特性和电子接受特性而备受关注。最近,许多含硼材料被用作热激活延迟荧光(TADF)OLED应用的发光材料。在本综述中,对用于蓝色TADF OLED的基于硼受体的推拉小分子进行了综述,涵盖了它们不同类型的受体、分子设计、结构-性能关系、材料性能和器件性能。此外,还讨论了硼受体对于解决蓝色TADF OLED关键问题的重要性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7b3/7248410/eaae8ee851fa/fchem-08-00373-g0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7b3/7248410/a78f7b355459/fchem-08-00373-g0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7b3/7248410/a17cd6a8f2df/fchem-08-00373-g0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7b3/7248410/c19e456ba543/fchem-08-00373-g0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7b3/7248410/2abc1300d09f/fchem-08-00373-g0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7b3/7248410/7ea7ae408c53/fchem-08-00373-g0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7b3/7248410/da867c8058bb/fchem-08-00373-g0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7b3/7248410/d76af5abf530/fchem-08-00373-g0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7b3/7248410/fe891bdbe795/fchem-08-00373-g0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7b3/7248410/eaae8ee851fa/fchem-08-00373-g0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7b3/7248410/a78f7b355459/fchem-08-00373-g0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7b3/7248410/a17cd6a8f2df/fchem-08-00373-g0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7b3/7248410/c19e456ba543/fchem-08-00373-g0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7b3/7248410/2abc1300d09f/fchem-08-00373-g0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7b3/7248410/7ea7ae408c53/fchem-08-00373-g0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7b3/7248410/da867c8058bb/fchem-08-00373-g0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7b3/7248410/d76af5abf530/fchem-08-00373-g0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7b3/7248410/fe891bdbe795/fchem-08-00373-g0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7b3/7248410/eaae8ee851fa/fchem-08-00373-g0009.jpg

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Adv Mater. 2020 Mar;32(9):e1906614. doi: 10.1002/adma.201906614. Epub 2020 Jan 24.
2
Multiple Resonance Effect-Induced Sky-Blue Thermally Activated Delayed Fluorescence with a Narrow Emission Band.多共振效应诱导的具有窄发射带的天蓝色热激活延迟荧光
Org Lett. 2019 Dec 6;21(23):9311-9314. doi: 10.1021/acs.orglett.9b03342. Epub 2019 Oct 15.
3
Multi-Resonance Induced Thermally Activated Delayed Fluorophores for Narrowband Green OLEDs.
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Chem Sci. 2024 Jul 8;15(31):12606-12615. doi: 10.1039/d3sc06989c. eCollection 2024 Aug 7.
4
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Nat Commun. 2024 Apr 6;15(1):2977. doi: 10.1038/s41467-024-47307-3.
5
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Beilstein J Org Chem. 2023 Dec 7;19:1849-1857. doi: 10.3762/bjoc.19.137. eCollection 2023.
6
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6
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