手性“三层夹心”Nd(III)纳米簇的构建，对 Co(II)具有高近红外发光灵敏度。
Construction of Chiral "Triple-Decker" Nd(III) Nanocluster with High NIR Luminescence Sensitivity toward Co(II).
机构信息
College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China.
The University of Texas at Austin, Department of Chemistry and Biochemistry, 1 University Station A5300, Austin, Texas 78712, United States.
出版信息
Inorg Chem. 2020 Jul 6;59(13):8652-8656. doi: 10.1021/acs.inorgchem.0c01146. Epub 2020 Jun 21.
One Nd(III) complex [NdL(OAc)] () was synthesized from a conjugate Schiff base ligand HL. It shows a chiral "triple-decker" structure (1.1 × 1.2 × 1.8 nm) with Nd(III) ions sandwiched between the Schiff base ligands. exhibits NIR Nd(III) luminescence, and the LMET efficiency is calculated to be 13.8%. It displays high luminescence sensitivity and selectivity to Co(II). The value and LOD of to Co(II) are 9.96 × 10 M and 0.97 μM, respectively.
合成了一个 Nd(III)配合物NdL(OAc)，该配合物来自共轭席夫碱配体 HL。它具有手性“三层”结构(1.1×1.2×1.8nm)，Nd(III)离子夹在席夫碱配体之间。该配合物具有近红外 Nd(III)发光性质，LMET 效率计算为 13.8%。它对 Co(II)表现出高的发光灵敏度和选择性。配合物对 Co(II)的 值和 LOD 分别为 9.96×10 M 和 0.97μM。
Zotero 插件