School of Biosystems Engineering and Food Science, Zhejiang University, Hangzhou, 310058, P. R. China.
Zhejiang A&F University, Hangzhou, 311300, P. R. China.
Small. 2020 Aug;16(33):e1907282. doi: 10.1002/smll.201907282. Epub 2020 Jun 25.
Recycling of noble metal from waste materials, namely from electronic wastes (e-waste), spent catalyst, and industrial wastewater, is attracting growing attention due to the scarcity, economic importance, and criticality of those noble metals. Traditional techniques reported to date require toxic reagent and strict extraction conditions, which deeply hinders the development of precious metal recovery in complex environments. Here, an approach is proposed that uses flexible metallic transition metal dichalcogenide (TMD) paper, which provides abundant active sites for spontaneous adsorption and reduction of noble metal ions, as an Alchemy-inspired template to recover noble metal in an efficient and green way without the aid of reductant and heating. The metallic TMD (MoS , WS ) paper is shown to rapidly extract five noble metal ions (Au, Pd, Pt, Ag, and Ru) from complex samples containing various interferents. This unique property endows the metallic TMD paper with gifted ability in extracting gold from e-waste, and recovering platinum group metals (palladium and platinum) from spent catalysts, which provides a blueprint for the design of next-generation green platforms for noble metal regeneration.
从废料中回收贵金属,即从电子废物(电子垃圾)、废催化剂和工业废水中回收贵金属,由于这些贵金属的稀缺性、经济重要性和关键,正引起越来越多的关注。迄今为止报道的传统技术需要有毒试剂和严格的提取条件,这严重阻碍了复杂环境中贵金属回收的发展。在这里,提出了一种使用柔性金属过渡金属二硫属化物(TMD)纸作为灵感源自炼金术的模板,在无需还原剂和加热的情况下,以高效和绿色的方式回收贵金属的方法。事实证明,金属 TMD(MoS2、WS2)纸能够从含有各种干扰物的复杂样品中快速提取五种贵金属离子(Au、Pd、Pt、Ag 和 Ru)。这种独特的性质使金属 TMD 纸具有从电子废物中提取金和从废催化剂中回收铂族金属(钯和铂)的天赋能力,为设计下一代绿色贵金属再生平台提供了蓝图。