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可持续且有选择性的贵金属回收现代方法。

Sustainable and Selective Modern Methods of Noble Metal Recycling.

机构信息

Department of Chemistry, University of Helsinki, P.O. Box 55 (A. I. Virtasen aukio 1), 00014, Helsinki, Finland.

Faculty of Chemistry and Chemical Technology, University of Ljubljana, Večna pot 113, 1000, Ljubljana, Slovenia.

出版信息

Angew Chem Int Ed Engl. 2023 Jan 26;62(5):e202214453. doi: 10.1002/anie.202214453. Epub 2022 Dec 14.

Abstract

Noble metals exhibit broad arrange of applications in industry and several aspects of human life which are becoming more and more prevalent in modern times. Due to their limited sources and constantly and consistently expanding demand, recycling of secondary and waste materials must accompany the traditional mineral extractions. This Minireview covers the most recent solvometallurgical developments in regeneration of Pd, Pt, Rh, Ru, Ir, Os, Ag and Au with emphasis on sustainability and selectivity. Processing-by selective oxidative dissolution, reductive precipitation, solvent extraction, co-precipitation, membrane transfer and trapping to solid media-of eligible multi-metal substrates for recycling from waste printed circuit boards to end-of-life automotive catalysts are discussed. Outlook for possible future direction for noble metal recycling is proposed with emphasis on sustainable approaches.

摘要

贵金属在工业和现代人类生活的多个方面都有广泛的应用,由于其来源有限,而需求不断增长且持续,因此必须对二次和废弃材料进行回收利用,以配合传统的矿物提取。这篇迷你综述涵盖了最近在 Pd、Pt、Rh、Ru、Ir、Os、Ag 和 Au 的再生方面的溶剂冶金发展,重点关注可持续性和选择性。讨论了从废印刷电路板到报废汽车催化剂的多金属基底的合适选择,通过选择性氧化溶解、还原沉淀、溶剂萃取、共沉淀、膜转移和固定相捕获等方法进行处理,以实现从废弃物中回收贵金属。提出了贵金属回收可能的未来发展方向,重点是可持续方法。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f923/10107291/b9ebdf045482/ANIE-62-0-g001.jpg

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