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基于碳纳米管负载镍锌铁氧体粒子的静电纺丝 PU 纳米纤维复合材料作为一种吸附剂用于空气中硫化氢的去除。

Electrospun PU nanofiber composites based on carbon nanotubes decorated with nickel-zinc ferrite particles as an adsorbent for removal of hydrogen sulfide from air.

机构信息

Department of Chemistry, Imam Hossein University, Tehran, Iran.

Department of Textile Engineering, Yazd University, P.O. Box 89195-741, Yazd, Iran.

出版信息

Environ Sci Pollut Res Int. 2020 Oct;27(28):35515-35525. doi: 10.1007/s11356-020-09324-9. Epub 2020 Jun 27.

Abstract

This study focuses on the synthesis of carbon nanotubes decorated with nickel-zinc ferrites and fabrication of polyurethane (PU) nanofiber containing CNT-ferrite composites as highly efficient adsorbents for removal of hydrogen sulfide. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transformed infrared (FTIR) spectroscopy, and powder X-ray diffraction (PXRD) are used to perform microstructural and morphological characterization of the electrospun nanofibrous composites. To show the efficiency of the composite as an adsorbent, a breakthrough test is carried out. It is shown that the PU-CNT-ferrite composites are fabricated almost uniformly with an average fiber diameter of 320 nm and exhibit significant HS breakthrough capacity (498 mgHS/g) compared to both the pristine PU and PU-CNT nanofibers. These electrospun nanofibers based on CNT-ferrite composites, already studied for HS adsorption with promising results, open up new and interesting perspective into the design and fabrication of highly efficient membrane for practical application in the processes of air purification.

摘要

本研究专注于合成镍锌铁氧体修饰的碳纳米管,并制备含有 CNT-铁氧体复合材料的聚氨酯(PU)纳米纤维,作为高效去除硫化氢的吸附剂。扫描电子显微镜(SEM)、透射电子显微镜(TEM)、傅里叶变换红外(FTIR)光谱和粉末 X 射线衍射(PXRD)用于对电纺纳米纤维复合材料进行微观结构和形态表征。为了展示复合材料作为吸附剂的效率,进行了突破测试。结果表明,PU-CNT-铁氧体复合材料的制备几乎均匀,平均纤维直径为 320nm,与原始的 PU 和 PU-CNT 纳米纤维相比,表现出显著的 HS 突破容量(498mgHS/g)。这些基于 CNT-铁氧体复合材料的电纺纳米纤维已经在 HS 吸附方面进行了研究,取得了有前景的结果,为设计和制造高效膜开辟了新的有趣视角,可实际应用于空气净化过程。

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