Belgacem Chihaoui, Tarres Quim, Espinach Francesc Xavier, Mutjé Pere, Boufi Sami, Delgado-Aguilar Marc
Faculty of Science, University of Sfax, LMSE, Sfax BP 802-3018, Tunisia.
LEPAMAP Research Group, Department of Chemical Engineering, University of Girona, 17003 Girona, Spain.
Polymers (Basel). 2020 Jun 26;12(6):1423. doi: 10.3390/polym12061423.
In this work, date palm waste (DPW) stemming from the annual pruning of date palm was used as reinforcing filler in polypropylene (PP) matrix at 40% /. Three pre-treatment routes were performed for the DPW, namely (i) defibration, (ii) soft alkali treatment, and (iii) enzymatic treatment, to obtain date palm fibers (DPF) and to investigate the effect of each process on their chemical composition, which will ultimately affect the mechanical properties of the resulting composites. The enzymatic and alkali treatment, combined with maleated polypropylene (MAPP) as a coupling agent, resulted in a composite with higher strength and stiffness than the neat PP. The differences in the reinforcing effect were explained by the change in the morphology of DPF and their chemical surface composition according to the selected treatment of DPW. Enzymatic treatment maximized the tensile strength of the compound as a consequence of an improvement in the interfacial shear strength and the intrinsic resistance of the fibers.
在本研究中,将源自枣椰树年度修剪的枣椰树废料(DPW)以40%的比例用作聚丙烯(PP)基体中的增强填料。对DPW进行了三种预处理途径,即(i)解纤,(ii)软碱处理,以及(iii)酶处理,以获得枣椰树纤维(DPF),并研究每个过程对其化学成分的影响,这最终将影响所得复合材料的机械性能。酶处理和碱处理,再结合马来酸酐接枝聚丙烯(MAPP)作为偶联剂,得到了一种比纯PP具有更高强度和刚度的复合材料。根据所选的DPW处理方式,DPF形态及其化学表面组成的变化解释了增强效果的差异。酶处理由于界面剪切强度和纤维固有抗性的提高而使复合材料的拉伸强度最大化。