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烟草秸秆粉/碱式硫酸镁晶须增强再生聚丙烯混杂复合材料:力学、热学及抗菌性能

Tobacco Stalk Flour/Magnesium Oxysulfate Whiskers Reinforced Hybrid Composites of Recycled Polypropylene: Mechanical and Thermal and Antibacterial Properties.

作者信息

Yuan Qinghua, Yang Wei, Ma Zhuwen, Huang Zhenrui, Cao Lin, Lin Zhidan, Zhang Peng

机构信息

Key Laboratory of Crop Genetic Improvement of Guangdong Province, Guangdong Provincial Engineering & Technology Research Center for Tobacco Breeding and Comprehensive Utilization, Crops Research Institute, Guangdong Academy of Agricultural Sciences, Guangzhou 510640, China.

Institute of Advanced Wear & Corrosion Resistant and Functional Materials, Jinan University, Guangzhou 510632, China.

出版信息

Polymers (Basel). 2022 Feb 20;14(4):815. doi: 10.3390/polym14040815.

DOI:10.3390/polym14040815
PMID:35215728
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8962986/
Abstract

The present investigation utilizes tobacco stalks flour and magnesium oxysulfate whiskers as fillers to enhancers the recycle polypropylene through melt blending and injection molding. Studied the microscopic morphology, mechanical, thermal, and antibacterial properties of recycled polypropylene (rPP) based composites with different weight ratios of tobacco stalks flour (TSF) and magnesium oxysulfate whiskers (MOSw). Composites' morphological studies indicated that tobacco stalks flour, and recycled polypropylene has good adhesion, improving composites' mechanical properties. The addition of TSF did not significantly change the tensile strength of rPP, but it can effectively increase the flexural strength and flexural modulus. Compared with rPP, adding 30 wt% tobacco stalks flour to rPP can increase the flexural strength by about 32.74%. Meanwhile, the addition of magnesium oxysulfate whiskers further improves the material's tensile strength. An increase in tobacco stalks flour content in the rPP enhances the crystallization temperature and degree of crystallinity of the polymer. In addition, attributed to the existence of tobacco stalks flour hydrophilic and antibacterial ability, the water absorption of the hybrid composites was increased and obtained antibacterial ability. Hence, this study provides a new development idea for tobacco stalks r recycling and applications.

摘要

本研究利用烟草秸秆粉和硫酸镁晶须作为填料,通过熔融共混和注塑成型来增强回收聚丙烯。研究了具有不同重量比的烟草秸秆粉(TSF)和硫酸镁晶须(MOSw)的回收聚丙烯(rPP)基复合材料的微观形态、力学、热学和抗菌性能。复合材料的形态学研究表明,烟草秸秆粉与回收聚丙烯具有良好的附着力,提高了复合材料的力学性能。TSF的添加并未显著改变rPP的拉伸强度,但能有效提高其弯曲强度和弯曲模量。与rPP相比,向rPP中添加30 wt%的烟草秸秆粉可使弯曲强度提高约32.74%。同时,硫酸镁晶须的添加进一步提高了材料的拉伸强度。rPP中烟草秸秆粉含量的增加提高了聚合物的结晶温度和结晶度。此外,由于烟草秸秆粉的亲水性和抗菌能力的存在,杂化复合材料的吸水率增加并获得了抗菌能力。因此,本研究为烟草秸秆的回收利用和应用提供了新的发展思路。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9926/8962986/8ebd40c80e3f/polymers-14-00815-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9926/8962986/89d52317fa0a/polymers-14-00815-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9926/8962986/82716ffe156c/polymers-14-00815-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9926/8962986/ffcf91373cdb/polymers-14-00815-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9926/8962986/90a408dc18dc/polymers-14-00815-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9926/8962986/a8567d91deac/polymers-14-00815-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9926/8962986/68ecda551278/polymers-14-00815-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9926/8962986/ef17b37753ba/polymers-14-00815-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9926/8962986/8ebd40c80e3f/polymers-14-00815-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9926/8962986/89d52317fa0a/polymers-14-00815-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9926/8962986/82716ffe156c/polymers-14-00815-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9926/8962986/ffcf91373cdb/polymers-14-00815-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9926/8962986/90a408dc18dc/polymers-14-00815-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9926/8962986/a8567d91deac/polymers-14-00815-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9926/8962986/68ecda551278/polymers-14-00815-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9926/8962986/ef17b37753ba/polymers-14-00815-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9926/8962986/8ebd40c80e3f/polymers-14-00815-g008.jpg

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