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纤维状卤化物钙钛矿复合材料的纳微结构用于光子和光电应用。

Nano-Micro Dimensional Structures of Fiber-Shaped Luminous Halide Perovskite Composites for Photonic and Optoelectronic Applications.

机构信息

Department of Chemical Engineering and Advanced Research Center of Green Materials Science and Technology, National Taiwan University, Taipei, 10617, Taiwan.

Department of Chemical and Materials Engineering and Research Center of New Generation Light Driven Photovoltaic Modules, National Central University, Taoyuan, 32001, Taiwan.

出版信息

Macromol Rapid Commun. 2020 Nov;41(21):e2000157. doi: 10.1002/marc.202000157. Epub 2020 Jul 1.

Abstract

Perovskite nanomaterials have been revealed as highly luminescent structures regarding their dimensional confinement. In particular, their promising potential lies behind remarkable luminescent properties, including color tunability, high photoluminescence quantum yield, and the narrow emission band of halide perovskite (HP) nanostructures for optoelectronic and photonic applications such as lightning and displaying operations. However, HP nanomaterials possess such drawbacks, including oxygen, moisture, temperature, or UV lights, which limit their practical applications. Recently, HP-containing polymer composite fibers have gained much attention owing to the spatial distribution and alignment of HPs with high mechanical strength and ambient stability in addition to their remarkable optical properties comparable to that of nanocrystals. In this review, the fabrication methods for preparing nano-microdimensional HP composite fiber structures are described. Various advantages of the luminescent composite nanofibers are also described, followed by their applications for photonic and optoelectronic devices including sensors, polarizers, waveguides, lasers, light-down converters, light-emitting diode operations, etc. Finally, future directions and remaining challenges of HP-based nanofibers are presented.

摘要

钙钛矿纳米材料因其维度限制而被揭示为具有高发光性能的结构。特别是,它们在光电和光子应用方面具有显著的发光性能,包括颜色可调谐性、高光致发光量子产率和卤化物钙钛矿(HP)纳米结构的窄发射带,例如照明和显示操作,这使得它们具有广阔的应用前景。然而,HP 纳米材料存在一些缺点,如氧气、水分、温度或紫外线等,这些缺点限制了它们的实际应用。最近,由于 HP 与高机械强度和环境稳定性的聚合物复合纤维的空间分布和排列,以及与纳米晶体相当的优异光学性能,含 HP 的聚合物复合纤维引起了广泛关注。在这篇综述中,描述了制备纳米微尺寸 HP 复合纤维结构的方法。还描述了发光复合纳米纤维的各种优点,以及它们在包括传感器、偏振器、波导、激光、光下转换器、发光二极管操作等光子和光电器件中的应用。最后,提出了基于 HP 的纳米纤维的未来方向和存在的挑战。

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