Xu Chenbiao, Treadway Cal M, Murray Vanessa J, Minton Timothy K, Malaska Michael J, Cable Morgan L, Hofmann Amy E
Department of Chemistry and Biochemistry, Montana State University, Bozeman, Montana 59717, USA.
Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Dr., Pasadena, California 91109, USA.
J Chem Phys. 2020 Jun 28;152(24):244709. doi: 10.1063/5.0011958.
The inelastic scattering dynamics of the isobaric molecules, naphthalene (CH) and 2-octanone (CHO), on highly oriented pyrolytic graphite (HOPG) have been investigated as part of a broader effort to inform the inlet design of a mass spectrometer for the analysis of atmospheric gases during a flyby mission through the atmosphere of a planet or moon. Molecular beam-surface scattering experiments were conducted, and the scattered products were detected with the use of a rotatable mass spectrometer detector. Continuous, supersonic beams were prepared, with average incident translational energies, ⟨E⟩, of 247.3 kJ mol and 538.2 kJ mol for naphthalene and 268.6 kJ mol and 433.8 kJ mol for 2-octanone. These beams were directed toward an HOPG surface, held at 530 K, at incident angles, θ, of 30°, 45°, and 70°, and scattered products were detected as functions of their translational energies and scattering angles. The scattering dynamics of both molecules are very similar and mimic the scattering of atoms and small molecules on rough surfaces, where parallel momentum is not conserved, suggesting that the dynamics are dominated by a corrugated interaction potential between the incident molecule and the surface. The effective corrugation of the molecule-surface interaction is apparently caused by the structure of the incident molecule and the consequent myriad available energy transfer pathways between the molecule and the surface during a complex collision event. In addition, the HOPG surface contributes to the corrugation of the interaction potential because it can absorb significant energy from collisions with incident molecules that have high mass and incident energy. Small differences in the scattering dynamics of the two molecules are inferred to arise from the details of the molecule-surface interaction potential, with 2-octanone exhibiting dynamics that suggest a slightly stronger interaction with the surface than naphthalene. These results add to a growing body of work on the scattering dynamics of organic molecules on HOPG, from which insight into the hypervelocity sampling and analysis of such molecules may be obtained.
