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磁性可回收 TiO/SiO/γ-FeO/rGO 复合材料,具有显著增强的紫外-可见光光催化活性。

Magnetically Recoverable TiO/SiO/γ-FeO/rGO Composite with Significantly Enhanced UV-Visible Light Photocatalytic Activity.

机构信息

Department of Chemistry, Materials and Chemical Engineering, Politecnico di Milano, 20124 Milano, Italy.

Department of Chemistry, Sharif University of Technology, Tehran 145888-9694, Iran.

出版信息

Molecules. 2020 Jun 30;25(13):2996. doi: 10.3390/molecules25132996.

Abstract

In this paper, we report the preparation of a new composite (TiO/SiO/γ-FeO/rGO) with a high photocatalytic efficiency. The properties of the composite were examined by different analyses, including X-ray diffraction (XRD), field emission scanning electron microscope (FE-SEM), photoluminescence (PL), UV-Visible light diffuse reflectance spectroscopy, Fourier transform infrared spectroscopy (FTIR), Raman, vibrating-sample magnetometer (VSM), and nitrogen gas physisorption (BET) studies. The photocatalytic efficiency of the proposed composite was evaluated by the degradation of methylene blue under UV and visible light, and the results were compared with titanium dioxide (TiO), where degradation increased from 30% to 84% and 4% to 66% under UV and visible light, respectively. The significant increase in photocatalytic activity may be explained by the higher adsorption of dye on the surface of the composite and the higher separation and transfer of charge carriers, which in turn promote active sites and photocatalytic efficiency.

摘要

本文报道了一种具有高光催化效率的新型复合材料(TiO/SiO/γ-FeO/rGO)的制备。通过 X 射线衍射(XRD)、场发射扫描电子显微镜(FE-SEM)、光致发光(PL)、紫外-可见漫反射光谱、傅里叶变换红外光谱(FTIR)、拉曼、振动样品磁强计(VSM)和氮气物理吸附(BET)等多种分析手段对复合材料的性能进行了研究。通过在紫外光和可见光下降解亚甲基蓝评价了所提出的复合材料的光催化效率,并将结果与二氧化钛(TiO)进行了比较,分别在紫外光和可见光下的降解率从 30%增加到 84%和从 4%增加到 66%。光催化活性的显著提高可以用染料在复合材料表面的更高吸附以及载流子的更高分离和转移来解释,这反过来又促进了活性位点和光催化效率。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3132/7412534/c5f82cd58d9a/molecules-25-02996-g001.jpg

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