Hołyst Robert
Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland.
Soft Matter. 2005 Oct 21;1(5):329-333. doi: 10.1039/b509105e.
Pierre Gilles de Gennes was awarded a Nobel prize in physics "for discovering that methods developed for studying order phenomena in simple systems can be generalized to more complex forms of matter, in particular to liquid crystals and polymers". Thanks to his works "soft matter" became a new legitimate discipline in physics. Soft matter includes a vast range of materials, which cannot be classified as simple liquids or solids. Many soft matter systems exhibit partially broken translational and/or rotational symmetry. In others we observe mesoscopic self-assembling into supramolecular structures leading to viscoelastic behavior. The partial ordering with viscoelastic properties, topological and geometrical complexity, and long relaxations associated with broken symmetries and/or supramolecular assembling are the main features of these systems. Among them we find liquid crystals, gels, biological membranes, colloidal suspensions, polymer solutions and polymer melts and blends, surfactant solutions . Typical models used in soft matter theory are based on statistical mechanics and classical thermodynamics, supplemented by the theory of elasticity, hydrodynamics and thermodynamics of irreversible processes and also some elements of the field theory. In this short overview I would like to discuss three theoretical issues related to soft matter systems: interactions, the role of the entropy, and finally the order parameter description.
皮埃尔·吉勒·德热纳被授予诺贝尔物理学奖,“因其发现用于研究简单系统中有序现象的方法可以推广到更复杂的物质形式,特别是液晶和聚合物”。由于他的研究成果,“软物质”成为物理学中一门新的正统学科。软物质包括大量无法归类为简单液体或固体的材料。许多软物质系统表现出部分平移和/或旋转对称性破缺。在其他系统中,我们观察到介观自组装成超分子结构,从而导致粘弹性行为。具有粘弹性特性的部分有序性、拓扑和几何复杂性以及与对称性破缺和/或超分子组装相关的长弛豫时间是这些系统的主要特征。其中包括液晶、凝胶、生物膜、胶体悬浮液、聚合物溶液、聚合物熔体和共混物、表面活性剂溶液等。软物质理论中使用的典型模型基于统计力学和经典热力学,并辅以弹性理论、流体动力学以及不可逆过程热力学,还包括场论的一些元素。在这个简短的综述中,我想讨论与软物质系统相关的三个理论问题:相互作用、熵的作用,以及最后的序参量描述。