中国 146 个城市农田土壤中八种(类)重金属的污染评价及健康风险评估。
Pollution assessment and health risk evaluation of eight (metalloid) heavy metals in farmland soil of 146 cities in China.
机构信息
College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi, 830046, People's Republic of China.
Ecology Institute of Shandong Academy of Sciences, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250013, People's Republic of China.
出版信息
Environ Geochem Health. 2020 Nov;42(11):3949-3963. doi: 10.1007/s10653-020-00634-y. Epub 2020 Jul 10.
Heavy metals are the most important indicator for farmland soil; however, in China, few provincial and national scales of studies have been done on heavy metals. Herein, by retrieving published studies, we calculated the spatial distribution characters and evaluated the health risks of Cu, Zn, Cd, Ni, Pb, Cr, As, and Hg in the farmland soil of 146 cities in China. Results showed that (1) the range (mean) values of eight (metalloid) heavy metals were as follows in mg/kg: Cu 0.236-251.015 (44.604), Zn 0.151-1547.060 (154.203), Cd 0.014-39.100 (1.497), Ni 0.709-554.420 (41.968), Pb 0.327-495.400 (55.143), Cr 0.078-333.510 (70.093), As 0.836-60.000 (12.207), and Hg 0.008-12.190 (0.371). The coefficient of variation values of Cu, Cr, and As displayed moderate variation, and Zn, Cd, Ni, Pb, and Hg displayed high variation (142.148-364.960%). (2) the I values of As, Cu, Cd, Ni, Zn, Cr, Pb, and Hg were - 4.329 to 1.837, - 7.166 to 2.888, - 3.378 to 8.070, - 5.831 to 3.780, - 9.527 to 3.797, - 10.120 to 1.866, - 6.899 to 3.667, and - 3.681 to 6.966, respectively; in many cities, there was some degree of heavy metal pollution of the farmland soil such as Zn in Pingdu, Pb in Huludao, and Hg in Tongguan, Funshun, Huludao, and Qinglong (I > 3); there were no obvious spatial patterns of Cr, Ni, and As, and Zn, Cu, but Cd, Ni, Pb, and Hg mainly located in some cities in the southwest, central or eastern parts of China. (3) Health risk assessment showed that with the exception of Cd, Cr, and As by the respiration route and Ni, Cr, and As through skin exposure, the average amount of daily exposure of the eight (metalloid) heavy metals all showed values for children > adults, and the HQ and HI values were all lower than 1.0, indicating noncarcinogenic risks; calculation of carcinogenic risks showed there were no carcinogenic risks for As, Cr, Ni, and Cd; however, the value for Cr was the maximum and contributed 98.505% of the total.
重金属是农田土壤的最重要指标;然而,在中国,很少有省级和国家级规模的研究涉及重金属。在此,我们通过检索已发表的研究,计算了中国 146 个城市农田土壤中 Cu、Zn、Cd、Ni、Pb、Cr、As 和 Hg 的空间分布特征,并评估了其健康风险。结果表明:(1)八种(类)重金属的范围(平均值)值(mg/kg)如下:Cu 0.236-251.015(44.604)、Zn 0.151-1547.060(154.203)、Cd 0.014-39.100(1.497)、Ni 0.709-554.420(41.968)、Pb 0.327-495.400(55.143)、Cr 0.078-333.510(70.093)、As 0.836-60.000(12.207)和 Hg 0.008-12.190(0.371)。Cu、Cr 和 As 的变异系数值显示中等变异,而 Zn、Cd、Ni、Pb 和 Hg 则显示高度变异(142.148-364.960%)。(2)As、Cu、Cd、Ni、Zn、Cr、Pb 和 Hg 的 I 值分别为-4.329 至 1.837、-7.166 至 2.888、-3.378 至 8.070、-5.831 至 3.780、-9.527 至 3.797、-10.120 至 1.866、-6.899 至 3.667 和-3.681 至 6.966,在许多城市,农田土壤存在一定程度的重金属污染,如平度的 Zn、葫芦岛的 Pb 和潼关、凤顺、葫芦岛和青龙的 Hg(I>3);Cr、Ni 和 As 的空间模式不明显,而 Zn、Cu 则没有,但 Cd、Ni、Pb 和 Hg 主要分布在中国西南部、中部或东部的一些城市。(3)健康风险评估表明,除了通过呼吸途径的 Cd、Cr 和 As,以及通过皮肤暴露的 Ni、Cr 和 As 之外,八种(类)重金属的每日平均暴露量均为儿童>成人,HQ 和 HI 值均低于 1.0,表明非致癌风险;致癌风险计算表明,As、Cr、Ni 和 Cd 不存在致癌风险;然而,Cr 的值最大,占总风险的 98.505%。