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[中国新疆天山山脉土壤中微量类金属/重金属的来源识别与潜在生态危害评估]

[Source identification and potential ecological hazards assessment of trace metalloid/heavy metals in the soil of Tianshan Mountains, Xinjiang, China].

作者信息

Zhang Zhao-Yong, Jilili Abuduwailil, Jiang Feng-Qing

出版信息

Ying Yong Sheng Tai Xue Bao. 2014 Nov;25(11):3168-76.

Abstract

In this study, the contents of ten metalloid/heavy metals (As, Pb, Ni, Cd, Co, Hg, Cu, Mn, Zn and Cr) in soil samples collected from three sections including the central Urumqi-Akesu, eastern Blikun-Yiwu and western Zhaosu-Tekesi in Tianshan Mountains were determined, and their sources were identified by using typical statistical and multivariate statistical methods. The potential ecological risks of these heavy metals were assessed by employing pollution index method, potential ecological risk index and the background values of Tianshan Mountains, and Xinjiang, and also the Second National Standard of the Soil Qualities of China. The results showed that the contents of the heavy metals (Pb, Ni, Cd, Co, Hg, Cu, Mn Zn and Cr) and metalloid As were all higher than the soil background values of the Tianshan Mountain or Xinjiang, and their variation co- efficients belonged to the medium variation. In general, the contents of the ten metalloid/heavy metals in the soil of Tianshan Mountains were low. Principal component analysis showed that the ten metalloid/heavy metals could be identified as two principal components, among which PC1 (Cd, Pb, Hg, Mn and Zn) could be seen as 'human influence sources factor', PC2 (Cu, Ni, Cr, Co and As) as 'natural sources factor'. Mn and As had larger loads both in PC1 and PC2, and they could be co-influenced by human and natural sources. The pollution assessment showed that Hg and Cd in central Urumuqi-Akesu section and As in western Zhaosu-Tekesi section were all at alert level, while the other heavy metals in other sections were all at security level. From the comprehensive pollution indices (P(z)) of heavy metals, it was found that the ten metalloid/heavy metals in the soils of central Urumqi-Akesu section were at low pollution level, but those in the other two sections were at clean level. The potential ecological risk assessment showed that the potential ecological risk coefficient (E(i)r) and the ecological damage index (RI) of Hg and Cd in central Urumqi-Akesu section and that of As in western Zhaosu-Tekesi section were relatively high.

摘要

本研究测定了取自天山中部乌鲁木齐—阿克苏、东部布伦口—依吞布拉克和西部昭苏—特克斯三个区域的土壤样品中10种类金属/重金属(砷、铅、镍、镉、钴、汞、铜、锰、锌和铬)的含量,并采用典型统计和多元统计方法确定其来源。利用污染指数法、潜在生态风险指数以及天山、新疆土壤背景值和中国土壤环境质量二级标准,对这些重金属的潜在生态风险进行了评估。结果表明,重金属(铅、镍、镉、钴、汞、铜、锰、锌和铬)以及类金属砷的含量均高于天山或新疆土壤背景值,其变异系数属于中等变异。总体而言,天山土壤中10种类金属/重金属含量较低。主成分分析表明,10种类金属/重金属可分为两个主成分,其中PC1(镉、铅、汞、锰和锌)可视为“人为影响源因子”,PC2(铜、镍、铬、钴和砷)可视为“自然源因子”。锰和砷在PC1和PC2中均有较大载荷,可能受到人为和自然源的共同影响。污染评价显示,乌鲁木齐—阿克苏中部地区的汞和镉以及昭苏—特克斯西部地区的砷均处于警戒水平,而其他地区的其他重金属均处于安全水平。从重金属综合污染指数(P(z))来看,乌鲁木齐—阿克苏中部地区土壤中10种类金属/重金属处于轻度污染水平,而其他两个地区处于清洁水平。潜在生态风险评价表明,乌鲁木齐—阿克苏中部地区汞和镉以及昭苏—特克斯西部地区砷的潜在生态风险系数(E(i)r)和生态损害指数(RI)相对较高。

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