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绿色新型煤矿注浆加固材料基本性能试验研究

Experimental Study on the Basic Properties of a Green New Coal Mine Grouting Reinforcement Material.

作者信息

Zhu Xianxiang, Zhang Qi, Zhang Wenquan, Shao Jianli, Wang Zaiyong, Wu Xintao

机构信息

College of Mining and Safety Engineering, Shandong University of Science and Technology, Qingdao 266590, China.

State Key Laboratory of Mine Disaster Prevention and Control, Shandong University of Science and Technology, Qingdao 266590, China.

出版信息

ACS Omega. 2020 Jun 28;5(27):16722-16732. doi: 10.1021/acsomega.0c01626. eCollection 2020 Jul 14.

Abstract

Waste tires are internationally recognized as hazardous waste. Many waste tires storing in the open air for a long time will not only waste the land resources but also pollute the environment after the incineration. Meanwhile, the cumulative accumulation of fly ash in China has also been one of the largest sources of solid waste in coal mines. Under the action of high winds, the accumulated fly ash forms flying dust, which pollutes the environment and endangers human health. Herein, a new type of grouting material for floor reinforcement was developed based on solid waste products using the waste tire rubber particles and fly ash. Using this new material, disaster accidents such as flooding and casualties caused by the inrush of the floor-confined water due to floor fractures, activation, and expansion in the mining process can be greatly reduced, thereby ensuring the safety of coal mine production. The grout body was prepared using a large amount of fly ash, waste tire rubber particles and clay, and mixing additives. The ratio optimization test, uniaxial compressive strength test, permeability characteristic test, stability test, and microanalysis of mine water environment were performed. From the test results, the macrophysical and chemical properties including optimal mix ratio, compressive strength, permeability coefficient, and stability of mine water environment were obtained. The microstructural properties of the grouts were analyzed using scanning electron microscopy microanalysis methods. Considering the situation of the coal floor and attempting to use as many solid waste products as possible, the optimized proportion that can meet the requirements of low cost, high bonds, and dense filling is as follows: 20% of rubber particles, 65% of fly ash, 15% of clay, and 1% of nanosilica. Furthermore, this study can provide scientific reference for large-scale floor grouting reinforcement and large-scale utilization of solid waste products.

摘要

废旧轮胎在国际上被认定为危险废物。大量废旧轮胎长期露天存放,不仅会浪费土地资源,焚烧后还会污染环境。与此同时,我国粉煤灰的累计堆存量也一直是煤矿固体废弃物的最大来源之一。在大风作用下,堆积的粉煤灰形成扬尘,污染环境,危害人体健康。在此,基于固体废弃物产品,利用废旧轮胎橡胶颗粒和粉煤灰开发了一种新型的底板加固注浆材料。使用这种新材料,可以大大减少采矿过程中因底板破裂、活化和膨胀导致底板承压水涌入而引发的水灾和人员伤亡等灾害事故,从而确保煤矿生产安全。注浆体采用大量粉煤灰、废旧轮胎橡胶颗粒、黏土以及混合添加剂制备而成。进行了配比优化试验、单轴抗压强度试验、渗透特性试验、稳定性试验以及矿井水环境微观分析。从试验结果中,得出了包括最佳配比、抗压强度、渗透系数以及矿井水环境稳定性等宏观物理和化学性质。采用扫描电子显微镜微观分析方法对注浆体的微观结构性质进行了分析。考虑到煤层底板情况并尽可能多地使用固体废弃物产品,能够满足低成本、高粘结性和密实充填要求的优化配比为:橡胶颗粒20%、粉煤灰65%、黏土15%、纳米二氧化硅1%。此外,本研究可为大规模底板注浆加固及固体废弃物产品的大规模利用提供科学参考。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/98e2/7364709/9ee40103a633/ao0c01626_0001.jpg

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