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关于与光合产氧相关的氧/氧同位素效应。

On the O/O isotope effect associated with photosynthetic O production.

作者信息

Tcherkez Guillaume, Farquhar Graham D

机构信息

Plateforme Métabolisme-Métabolome, IFR87, Université Paris-Sud XI, Orsay 91405, France.

Environmental Biology Group, Research School of Biological Sciences, Australian National University, Canberra, ACT 2601, Australia.

出版信息

Funct Plant Biol. 2007 Dec;34(11):1049-1052. doi: 10.1071/FP07168.

DOI:10.1071/FP07168
PMID:32689433
Abstract

While photosynthetically evolved O has been repeatedly shown to have nearly the same oxygen isotope composition as source water so that there is no corresponding O/O isotope effect, some recent O-enrichment studies suggest that a large isotope effect may occur, thus feeding a debate in the literature. Here, the classical theory of isotope effects was applied to show that a very small isotope effect is indeed expected during O production. Explanations of the conflicting results are briefly discussed.

摘要

虽然光合产生的氧已被反复证明其氧同位素组成与源水几乎相同,因此不存在相应的氧/氧同位素效应,但最近的一些氧富集研究表明可能会出现较大的同位素效应,这引发了文献中的一场争论。在此,应用经典的同位素效应理论表明,在氧产生过程中确实预期会有非常小的同位素效应。对相互矛盾的结果的解释也进行了简要讨论。

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引用本文的文献

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Studying the oxidation of water to molecular oxygen in photosynthetic and artificial systems by time-resolved membrane-inlet mass spectrometry.通过时间分辨膜进样质谱法研究光合系统和人工系统中水分子氧化生成分子氧的过程。
Front Plant Sci. 2013 Nov 26;4:473. doi: 10.3389/fpls.2013.00473.