双（甲醇）（内消旋-四苯基卟吩inato）锰（III）六氯锑酸盐双（四氯乙烷）溶剂化物的结构
Structure of bis(methanol)(meso-tetraphenylporphinato)manganese(III) hexachloroantimonate bis(tetrachloroethane) solvate.
作者信息
Scheidt W R, Pearson W B, Gosal N
机构信息
Department of Chemistry, University of Notre Dame, Indiana 46556.
出版信息
Acta Crystallogr C. 1988 May 15;44 ( Pt 5):927-9. doi: 10.1107/s0108270187012411.
[Mn(C44H30N4)(CH3OH)2] [SbCl6].2C2H2Cl4, Mr = 1401.93, triclinic, P1, a = 11.104 (3), b = 12.086 (6), c = 12.619 (4) A, alpha = 115.33 (3), beta = 104.75 (2), gamma = 91.75 (3) degrees, V = 1461.3 A3, Z = 1, Dm = 1.58, D chi = 1.59 Mg m-3, lambda(Mo K alpha) = 0.71073 A, mu = 1.359 mm-1, F(000) = 698, T = 293 K, R = 0.079 for 4822 unique observed reflections. The manganese ion is coordinated to two methanol oxygens, Mn--O = 2.283 (5) A, and four porphinato nitrogen atoms, average Mn--N = 2.002 (5) A.
[Mn(C₄₄H₃₀N₄)(CH₃OH)₂][SbCl₆]·2C₂H₂Cl₄，Mr = 1401.93，三斜晶系，P1，a = 11.104(3)，b = 12.086(6)，c = 12.619(4) Å，α = 115.33(3)，β = 104.75(2)，γ = 91.75(3)°，V = 1461.3 ų，Z = 1，Dm = 1.58，Dc = 1.59 Mg m⁻³，λ(Mo Kα) = 0.71073 Å，μ = 1.359 mm⁻¹，F(000) = 698，T = 293 K，对4822个独立观测反射，R = 0.079。锰离子与两个甲醇氧原子配位，Mn—O = 2.283(5) Å，与四个卟啉氮原子配位，平均Mn—N = 2.002(5) Å。
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