水杨醛缩氨基硫脲的结构
Structure of salicylaldehyde thiosemicarbazone.
作者信息
Chattopadhyay D, Mazumdar S K, Banerjee T, Ghosh S, Mak T C
机构信息
Crystallography and Molecular Biology Division, Saha Institute of Nuclear Physics, Calcutta, India.
出版信息
Acta Crystallogr C. 1988 Jun 15;44 ( Pt 6):1025-8. doi: 10.1107/s010827018800040x.
C8H9N3OS, monoclinic, C2/c, a = 14.206 (3), b = 14.244 (4), c = 10.457 (4) A, beta = 116.18(2) degrees, V = 1898.9 (8) A3, Z = 8, Dm = 1.387, D chi = 1.366 g cm-3, lambda(Mo K alpha) = 0.71069 A, mu = 2.90 cm-1, F(000) = 816.0, T = 298 K, final R = 0.0429 for 1322 observed reflections. The S and hydrazinic N atoms lie trans. The lowering of antibacterial activity compared to that of 4-phenylthiosemicarbazide may be correlated with the decrease in negative charge on the hydrazinic N atom. The crystal structure is stabilized by hydrogen bonding, stacking interactions and van der Waals forces.
C8H9N3OS，单斜晶系，C2/c空间群，a = 14.206 (3)，b = 14.244 (4)，c = 10.457 (4) Å，β = 116.18(2)°，V = 1898.9 (8) ų，Z = 8，Dm = 1.387，Dc = 1.366 g cm⁻³，λ(Mo Kα) = 0.71069 Å，μ = 2.90 cm⁻¹，F(000) = 816.0，T = 298 K，对1322个观测反射的最终R值为0.0429。硫原子和肼基氮原子呈反式排列。与4-苯基硫代氨基脲相比，抗菌活性的降低可能与肼基氮原子上负电荷的减少有关。晶体结构通过氢键、堆积相互作用和范德华力得以稳定。
Zotero 插件