Vavra Eric, Puerto Maura, Biswal Sibani L, Hirasaki George J
Department of Chemical and Biomolecular Engineering, Rice University, 6100 Main St., MS-362, Houston, TX, 77005, USA.
Sci Rep. 2020 Jul 31;10(1):12930. doi: 10.1038/s41598-020-69511-z.
The apparent viscosity of viscous heavy oil emulsions in water can be less than that of the bulk oil. Microfluidic flooding experiments were conducted to evaluate how alkali-surfactant-foam enhanced oil recovery (ASF EOR) of heavy oil is affected by emulsion formation. A novel phase-behavior viscosity map-a plot of added salinity vs. soap fraction combining phase behavior and bulk apparent viscosity information-is proposed as a rapid and convenient method for identifying suitable injection compositions. The characteristic soap fraction, [Formula: see text], is shown to be an effective benchmark for relating information from the phase-viscosity map to expected ASF flood test performance in micromodels. Characteristically more hydrophilic cases were found to be favorable for recovering oil, despite greater interfacial tensions, due to wettability alteration towards water-wet conditions and the formation of low apparent-viscosity oil-in-water (O/W) macroemulsions. Wettability alteration and bubble-oil pinch-off were identified as contributing mechanisms to the formation of these macroemulsions. Conversely, characteristically less hydrophilic cases were accompanied by a large increase in apparent viscosity due to the formation of water-in-oil (W/O) macroemulsions.
粘性稠油在水中形成的乳液的表观粘度可能低于原油的表观粘度。进行了微流控驱油实验,以评估碱-表面活性剂-泡沫提高稠油采收率(ASF提高采收率)受乳液形成的影响。提出了一种新颖的相行为粘度图——一种将相行为和整体表观粘度信息相结合的添加盐度与皂含量的关系图——作为确定合适注入组合物的快速便捷方法。特征皂含量[公式:见原文]被证明是一种有效的基准,可将相-粘度图中的信息与微模型中预期的ASF驱油试验性能相关联。尽管界面张力较大,但由于向水湿条件的润湿性改变以及形成低表观粘度的水包油(O/W)宏观乳液,发现典型的更亲水情况有利于采油。润湿性改变和气泡-油夹断被确定为这些宏观乳液形成的作用机制。相反,典型的亲水性较低的情况由于形成油包水(W/O)宏观乳液而伴随着表观粘度的大幅增加。