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Gemini表面活性剂在稠油开发中的应用与合成

Application and Synthesis of Gemini Surfactant in Heavy Oil Development.

作者信息

Liu Peng, Li Xianghong, Li Hua, Liu Shanghao, Wang Jiaqin, Zhang Peng

机构信息

Chongqing University of Science and Technology, Chongqing 401331, China.

出版信息

ACS Omega. 2025 Feb 27;10(9):8832-8842. doi: 10.1021/acsomega.4c11144. eCollection 2025 Mar 11.

Abstract

Gemini surfactants have many potential applications in the viscosity reduction of heavy oils due to their unique structure, which appears to consist of two single-chain surfactant molecules. This paper introduces the viscosity reduction mechanism of gemini surfactants and the research progress of four types of Gemini surfactants used in the viscosity reduction of heavy oils at home and abroad. The study found that in the formation water containing calcium and magnesium ions with a salinity of more than 30000 mg/L, the added amount of gemini anionic surfactant was 0.4-0.5%, the viscosity reduction rate could reach more than 90%, and ultralow interfacial tension (10 orders of magnitude) was achieved. Based on the above advantages, the synthesis and physicochemical properties of gemini anionic surfactants are summarized. Finally, the difficulties in synthesizing anionic gemini surfactants are summarized, and their future development trend is given.

摘要

由于其独特的结构,双子表面活性剂似乎由两个单链表面活性剂分子组成,在稠油降粘方面有许多潜在应用。本文介绍了双子表面活性剂的降粘机理以及国内外用于稠油降粘的四类双子表面活性剂的研究进展。研究发现,在盐度大于30000mg/L的含钙镁离子地层水中,双子阴离子表面活性剂的添加量为0.4-0.5%时,降粘率可达90%以上,并能实现超低界面张力(10个数量级)。基于上述优点,总结了双子阴离子表面活性剂的合成及理化性质。最后,总结了合成阴离子双子表面活性剂的难点,并给出了其未来发展趋势。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6ad0/11904653/25798a9bbd38/ao4c11144_0001.jpg

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