Zhang Songlin, Ma Yan, Suresh Lakshmi, Hao Ayou, Bick Michael, Tan Swee Ching, Chen Jun
Department of Bioengineering, University of California, Los Angeles, Los Angeles, California 90095, United States.
National & Local Joint Engineering Research Center of Technical Fiber Composites for Safety and Protection, School of Textiles and Clothing, Nantong University, Nantong 226019, P.R. China.
ACS Nano. 2020 Aug 25;14(8):9282-9319. doi: 10.1021/acsnano.0c03268. Epub 2020 Aug 17.
As an excellent candidate for lightweight structural materials and nonmetal electrical conductors, carbon nanotube reinforced carbon matrix (CNT/C) composites have potential use in technologies employed in aerospace, military, and defense endeavors, where the combinations of light weight, high strength, and excellent conductivity are required. Both polymer infiltration pyrolysis (PIP) and chemical vapor infiltration (CVI) methods have been widely studied for CNT/C composite fabrications with diverse focuses and various modifications. Progress has been reported to optimize the performance of CNT/C composites from broad aspects, including matrix densification, CNT alignment, microstructure control, and interface engineering, . Recent approaches, such as using resistance heating for PIP or CVI, contribute to the development of CNT/C composites. To deliver a timely and up-to-date overview of CNT/C composites, we have reviewed the most recent trends in fabrication processes, summarized the mechanical reinforcement mechanism, and discussed the electrical and thermal properties, as well as relevant case studies for high-temperature applications. Conclusions and perspectives addressing future routes for performance optimization are also presented. Hence, this review serves as a rundown of recent advances in CNT/C composites and will be a valuable resource to aid future developments in this field.
作为轻质结构材料和非金属导电体的优秀候选材料,碳纳米管增强碳基(CNT/C)复合材料在航空航天、军事和国防等需要轻质、高强度和优异导电性相结合的技术领域具有潜在应用价值。聚合物浸渍热解(PIP)和化学气相浸渍(CVI)方法都已针对CNT/C复合材料的制备进行了广泛研究,研究重点各异且有各种改进。据报道,已从包括基体致密化、碳纳米管排列、微观结构控制和界面工程等广泛方面优化了CNT/C复合材料的性能。最近的方法,如在PIP或CVI中使用电阻加热,推动了CNT/C复合材料的发展。为了及时、全面地概述CNT/C复合材料,我们回顾了制造工艺的最新趋势,总结了机械增强机制,并讨论了其电学和热学性能以及高温应用的相关案例研究。还给出了关于性能优化未来路线的结论和展望。因此,本综述概述了CNT/C复合材料的最新进展,并将成为有助于该领域未来发展的宝贵资源。