Rational Design and Bulk Synthesis of Water-Containing Supramolecular Polymers.

The utilization of structural water in chemical self-assembly has not only effectively eliminated the negative influences of solvents from solutions or gels but has also provided new insight into the fabrication of new materials in bulk. However, up to now, supramolecular polymerization triggered by structural water has been dominated more by serendipity than rational design. After carefully analyzing the chemical structures of artificial monomers and gaining a deep understanding of the water-triggered assembly process, we report herein the bulk formation of polymeric materials from water and low-molecular weight monomers by rational design instead of serendipity.