Park Yu Jung, Kim Minseong, Song Aeran, Kim Jin Young, Chung Kwun-Bum, Walker Bright, Seo Jung Hwa, Wang Dong Hwan
Department of Materials Physics, Dong-A University, Busan 49315, Republic of Korea.
School of Integrative Engineering, Chung-Ang University, Seoul 06974, Republic of Korea.
ACS Appl Mater Interfaces. 2020 Aug 5;12(31):35175-35180. doi: 10.1021/acsami.0c05537. Epub 2020 Jul 27.
The class of organic-inorganic lead halides with perovskite crystal structures has recently emerged as promising materials for a variety of practical optoelectronic applications. In particular, hybrid halide perovskite quantum dots possess excellent intrinsic optoelectronic properties such as high color purity (full width at half-maximum of 24.59 nm) and photoluminescence quantum yields (92.7%). In this work, we demonstrate the use of perovskite quantum dot materials as an emissive layer of hybrid light-emitting transistors. To investigate the working mechanism of perovskite quantum dots in light-emitting transistors, we investigated the electrical and optical characteristics under both p-channel and n-channel operation. Using these materials, we have achieved perovskite quantum dot light-emitting transistors with high electron mobilities of up to 12.06 cm·V s, high brightness of up to 1.41 × 10 cd m, and enhanced external quantum efficiencies of up to 1.79% operating at a source-drain potential of 40 V.
具有钙钛矿晶体结构的有机-无机铅卤化物类材料最近已成为用于各种实际光电子应用的有前景的材料。特别是,混合卤化铅钙钛矿量子点具有优异的固有光电子特性,如高色纯度(半高宽为24.59纳米)和光致发光量子产率(92.7%)。在这项工作中,我们展示了使用钙钛矿量子点材料作为混合发光晶体管的发光层。为了研究钙钛矿量子点在发光晶体管中的工作机制,我们研究了p沟道和n沟道操作下的电学和光学特性。使用这些材料,我们实现了钙钛矿量子点发光晶体管,其在40V的源漏电势下工作时,具有高达12.06厘米²·伏⁻¹·秒⁻¹的高电子迁移率、高达1.41×10⁴坎德拉·米⁻²的高亮度以及高达1.79%的增强外量子效率。