Lu Yao, Lu Liang, Qiu Genrui, Sun Chunwen
CAS Center for Excellence in Nanoscience, Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Sciences; Beijing 100083, China.
School of Nanoscience and Technology, University of Chinese Academy of Sciences, Beijing 100049, China.
ACS Appl Mater Interfaces. 2020 Sep 2;12(35):39342-39351. doi: 10.1021/acsami.0c12052. Epub 2020 Aug 21.
In order to satisfy the increasing requirements on operation time of wearable and portable electronic devices, novel self-powered systems by integrating triboelectric nanogenerator (TENG) with an energy storage device have emerged as a promising technology to provide sustainable power. Here, a flexible sodium composite anode (Na@CC) was prepared by infusing the molten sodium into flexible sodiophilic carbon cloth. The symmetric cell with the Na@CC anode shows stable sodium plating and stripping for 400 h. The full cell with a flexible quasi-solid-state electrolyte, NaV(PO)@C nanofiber cathode, and Na@CC anode delivers an excellent rate capacity of 72.5 mAh g at 5 C and also exhibits stable cycling performance under different bent degrees. By combining with TENG to form a self-powered system, the flexible quasi-solid-state sodium battery can effectively store the pulse current and shows stable discharging capacity for over 100 cycles. The advanced flexible battery demonstrates its capability as a promising energy storage part in combination with TENGs and shows great potential in powerful flexible self-powered systems.