School of Chemical Sciences, National Institute of Science Education and Research (NISER), HBNI, P.O. Bhimpur-Padanpur, Via Jatni, District Khurda, Bhubaneswar, Odisha 752050, India.
J Org Chem. 2020 Oct 2;85(19):11997-12011. doi: 10.1021/acs.joc.0c01534. Epub 2020 Sep 1.
Organosulfur compounds are omnipresent in many drugs, natural products, and functional materials; therefore, methodologies of C-S bond formation reactions are desirable in synthesis. The recent trend to control many chemical reactions by cooperative multiple weak interactions have emerged as one of the popular topics in supramolecular catalysis. Herein, we have made a collection of literature which utilizes multiple noncovalent interactions like H-bonding, solvent bonding, S-H···π, C-H···π, π-π stacking, charge-transfer complexation, etc. toward aryl C-S bond-formation reactions.
有机硫化合物广泛存在于许多药物、天然产物和功能材料中；因此，C-S 键形成反应的方法在合成中是可取的。最近，通过协同多种弱相互作用来控制许多化学反应的趋势已成为超分子催化领域的热门话题之一。在这里，我们收集了利用多种非共价相互作用（如氢键、溶剂键、S-H···π、C-H···π、π-π 堆积、电荷转移络合等）进行芳基 C-S 键形成反应的文献。
