The College of Chemistry and Chemical Engineering, Yangzhou University, 180 Si-Wang-Ting Road, Yangzhou, 225002, P. R. China.
School of Mathematical and Physical Sciences, University of Technology Sydney City Campus, Broadway, Sydney, NSW 2007, Australia.
Chem Asian J. 2020 Oct 16;15(20):3239-3253. doi: 10.1002/asia.202000895. Epub 2020 Sep 21.
Nowadays, an ever-increasing variety of organic contaminants in water has caused hazards to the ecological environment and human health. Many of them are persistent and non-biodegradable. Various techniques have been studied for sewage treatment, including biological, physical and chemical methods. Photocatalytic advanced oxidation processes (AOPs) have received increasing attention due to their fast reaction rates and strong oxidation capability, low cost compared with the non-photolytic AOPs. This review is dedicated to summarizing up-to-date research progress in photocatalytic AOPs, such as Fenton or Fenton-like reaction, ozonation and sulfate radical-based advanced oxidation processes. Mechanisms and activation processes are discussed. Then, the paper summarizes photocatalytic materials and modification strategies, including defect chemistry, morphology control, heterostructure design, noble metal deposition. The future perspectives and challenges are also discussed.
如今,水中越来越多的有机污染物对生态环境和人类健康造成了危害。其中许多物质具有持久性和不可生物降解性。已经研究了多种污水处理技术,包括生物、物理和化学方法。光催化高级氧化工艺(AOPs)由于其快速的反应速率和较强的氧化能力,与非光解 AOPs 相比成本较低,因此受到越来越多的关注。本文综述了光催化 AOPs 的最新研究进展,如芬顿或类芬顿反应、臭氧氧化和基于硫酸根自由基的高级氧化工艺。讨论了其机制和活化过程。然后,本文总结了光催化材料和改性策略,包括缺陷化学、形貌控制、异质结构设计、贵金属沉积。还讨论了未来的展望和挑战。