Bolskis Evaldas, Adomavičiūtė Erika, Griškonis Egidijus, Norvydas Valdas
Faculty of Mechanical Engineering and Design, Kaunas University of Technology, Studentu Str. 56, 51424 Kaunas, Lithuania.
Faculty of Chemical Technology, Kaunas University of Technology, Radvilenu pl. 19, 50254 Kaunas, Lithuania.
Materials (Basel). 2020 Aug 29;13(17):3824. doi: 10.3390/ma13173824.
A possible approach for providing new properties for textiles is the insertion of natural ingredients into the textile product during the process of its manufacture. Myrrh has long been used in medicine as an antibacterial and antifungal material. Polylactide (PLA) is a thermoplastic synthetic biopolymer obtained from renewable resources-and due its biodegradability, is also widely used in medicine. In this study, films and multifilament yarns from modified biodegradable PLA granules with ethanolic and aqueous myrrh extracts were developed and characterized. Optical microscopy was used to determine the surface morphology of PLA/myrrh multifilament yarns. Tensile tests, ultraviolet-visible (UV-vis), differential scanning calorimetry (DSC) were applied to determine, consequently, mechanical, optical properties and degree of crystallinity of PLA/myrrh films and multifilament yarns. The chemical composition of PLA/myrrh multifilament yarns was estimated by Fourier-transform infrared (FTIR) spectroscopy method. The results showed that it is possible to form PLA melt-spun multifilament yarns with myrrh extract. The type of myrrh extract (ethanolic or aqueous) has a significant influence on the mechanical and optical properties of the PLA films and melt-spun yarns. The mechanical properties of PLA films and melt-spun multifilament yarns formed from PLA granules with aqueous myrrh extract decreased 19% and 21% more than PLA with ethanolic extract, respectively. Analysis of UV-vis spectra showed that, due to the yellow hue, the reflectance of PLA films and melt-spun PLA multifilament yarns modified with myrrh extracts decreased exponentially. The DSC test showed that multifilament yarns from PLA modified with aqueous extract had the highest degree of crystallization.
一种为纺织品赋予新特性的可行方法是在纺织品制造过程中将天然成分添加到产品中。没药长期以来在医学中用作抗菌和抗真菌材料。聚乳酸(PLA)是一种由可再生资源制得的热塑性合成生物聚合物,因其生物可降解性,也广泛应用于医学领域。在本研究中,制备并表征了含有乙醇提取物和水提取物的没药的改性可生物降解PLA颗粒制成的薄膜和复丝纱线。使用光学显微镜来确定PLA/没药复丝纱线的表面形态。随后,通过拉伸试验、紫外可见(UV-vis)光谱、差示扫描量热法(DSC)来测定PLA/没药薄膜和复丝纱线的机械性能、光学性能和结晶度。采用傅里叶变换红外(FTIR)光谱法估算PLA/没药复丝纱线的化学成分。结果表明,用没药提取物形成PLA熔纺复丝纱线是可行的。没药提取物的类型(乙醇提取物或水提取物)对PLA薄膜和熔纺纱线的机械性能和光学性能有显著影响。由含有水提取物的没药的PLA颗粒制成的PLA薄膜和熔纺复丝纱线的机械性能分别比含有乙醇提取物的没药的PLA降低了19%和21%。UV-vis光谱分析表明,由于黄色调,用没药提取物改性的PLA薄膜和熔纺PLA复丝纱线的反射率呈指数下降。DSC测试表明,用水提取物改性的PLA制成的复丝纱线具有最高的结晶度。