A portable electromagnetic heating-microplasma atomic emission spectrometry for direct determination of heavy metals in soil.

In this work, electromagnetic heating was firstly explored as sample introduction approach in portable microplasma-atomic emission spectrometer to achieve the direct, rapid analysis of soil sample. The device primarily consists of an electromagnetic heating unit, a dielectric barrier discharge (DBD) excitation source and an optical signal acquisition unit. A W-boat was used as an electromagnetic heating medium and sample carrier, and copper coil spiraled around the tube was used as magnetic induction coil. With applying a voltage on copper coil, W-boat was electromagnetically heated to vaporize analyte-containing species for sample introduction into the microplasma. The portable battery-powered device is controlled by a miniature touch screen computer with the main advantages of small size (40.5 cm (l) × 30 cm (w) × 15 cm (h).), light weight (less than 7 kg), low-power consumption (the average power consumption is 118 W). By this method, Hg, Cd and Pb in soil were simultaneously analyzed within 4 min. Under the optimal conditions, the limits of detection for Hg, Cd and Pb in soils were 8.0 μg/kg, 17.8 μg/kg and 3.5 mg/kg, respectively, meeting the requirements for environmental quality standards for soils of China. Different types of CRM soils were analyzed, demonstrating good accuracy, stability and utility of this method. This technique could be a promising and powerful tool for on-site, rapid analysis of heavy metals in soil even other solid samples. Electromagnetic heating mode provides a good alternative for solid sampling to develop portable, miniaturized atomic spectrometers for solid sample analysis.