Dreiss CÃ Cile A
Pharmaceutical Science Research Division, King's College London, Franklin-Wilkins Building, 150 Stamford Street, London, UKSE1 9NH.
Soft Matter. 2007 Jul 17;3(8):956-970. doi: 10.1039/b705775j.
Wormlike micelles are elongated flexible self-assembly structures formed by the aggregation of amphiphiles. Above a threshold concentration, they entangle into a dynamic network, reminiscent of polymer solutions, and display remarkable visco-elastic properties, which have been exploited in numerous industrial and technological fields. Relating the microstructure of these intricate structures with their bulk properties is still an ongoing quest. In this review, we present a classification of wormlike micelles, with a focus on novel systems and applications. We describe the current state of understanding of their linear rheology and give a detailed account of recent progress in small-angle neutron scattering, a particularly powerful technique to elucidate their microstructure on a wide range of length-scales.
蠕虫状胶束是由两亲分子聚集形成的细长柔性自组装结构。在临界浓度以上,它们缠结形成一个动态网络,类似于聚合物溶液,并表现出显著的粘弹性,这已在众多工业和技术领域得到应用。将这些复杂结构的微观结构与其整体性质联系起来仍是一个持续探索的问题。在这篇综述中,我们对蠕虫状胶束进行了分类,重点关注新型体系和应用。我们描述了目前对其线性流变学的理解状态,并详细介绍了小角中子散射的最新进展,这是一种特别强大的技术,可在广泛的长度尺度上阐明其微观结构。