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仿生流动驱动壳聚糖化学花园。

Bio-inspired flow-driven chitosan chemical gardens.

机构信息

Department of Physical Chemistry and Materials Science, University of Szeged, Rerrich Béla tér 1., Szeged, H-6720, Hungary.

Department of Applied and Environmental Chemistry, University of Szeged, Rerrich Béla tér 1., Szeged, H-6720, Hungary.

出版信息

Soft Matter. 2020 Sep 23;16(36):8325-8329. doi: 10.1039/d0sm01397h.

DOI:10.1039/d0sm01397h
PMID:32902544
Abstract

Organic chemical gardens of chitosan hydrogel develop upon injecting an acidic chitosan solution into an alkaline solution. Besides complex and budding structures, tubular hydrogel formations develop that exhibit periodic surface patterns. The underlying wrinkling instability is identified by its characteristic wavelength dependence on the diameter of the elastic material formed. The flow-driven conditions allow precise control over the structure that can help the design of soft bio-inspired materials. Our findings can also suggest a new direction in the field of chemobrionics.

摘要

壳聚糖水凝胶的有机化学花园是通过将酸性壳聚糖溶液注入碱性溶液中而形成的。除了复杂和萌芽的结构外,还会形成管状水凝胶,其具有周期性的表面图案。通过其对形成的弹性材料直径的特征波长依赖性,可以确定起皱不稳定性。流动驱动的条件可以精确控制结构,有助于设计软仿生材料。我们的发现也可以为化学生物电子学领域提供新的方向。

相似文献

1
Bio-inspired flow-driven chitosan chemical gardens.仿生流动驱动壳聚糖化学花园。
Soft Matter. 2020 Sep 23;16(36):8325-8329. doi: 10.1039/d0sm01397h.
2
Flow-driven Surface Instabilities of Tubular Chitosan Hydrogel.管状壳聚糖水凝胶的流动驱动表面不稳定性。
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引用本文的文献

1
Pattern selection by material aging: Modeling chemical gardens in two and three dimensions.材料老化的图案选择:二维和三维化学花园建模。
Proc Natl Acad Sci U S A. 2023 Jul 11;120(28):e2305172120. doi: 10.1073/pnas.2305172120. Epub 2023 Jul 3.
2
Controlled self-assembly of chemical gardens enables fabrication of heterogeneous chemobrionic materials.化学花园的可控自组装能够制造异质化学仿生材料。
Commun Chem. 2021 Oct 14;4(1):145. doi: 10.1038/s42004-021-00579-y.
3
Hierarchical Self-Assembly of Metal-Ion-Modulated Chitosan Tubules.
金属离子调控壳聚糖管状结构的分级自组装。
Langmuir. 2021 Nov 2;37(43):12690-12696. doi: 10.1021/acs.langmuir.1c02097. Epub 2021 Oct 21.
4
Flow-driven Surface Instabilities of Tubular Chitosan Hydrogel.管状壳聚糖水凝胶的流动驱动表面不稳定性。
Chemphyschem. 2021 Mar 3;22(5):488-492. doi: 10.1002/cphc.202000952. Epub 2021 Jan 27.