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热处理对激光熔覆Ni-65 WC涂层微观结构及摩擦腐蚀性能的影响

Effect of Heat Treatment on Microstructure and Tribocorrosion Performance of Laser Cladding Ni-65 WC Coating.

作者信息

Liu Ze, Liu Eryong, Du Shuangming, Li Congwei, Du Huiling, Bai Yaping

机构信息

School of Materials Science and Engineering, Xi'an University of Science and Technology, Xi'an 710054, China.

School of Materials Science and Chemical Engineering, Xi'an Technological University, Xi'an 710021, China.

出版信息

Scanning. 2020 Aug 20;2020:4843175. doi: 10.1155/2020/4843175. eCollection 2020.

Abstract

The Ni-65wt%WC cladding layers were prepared on the surface of Q235 using laser cladding technology, in which the effect of heat treatment on microstructure and tribocorrosion performance was investigated. The results showed that the coating is mainly consisted of Ni, WC, and WC, and a significant diffusion phenomenon is formed between the interfaces of WC/Ni matrix, benefited for the improvement of bonding layer between WC/Ni-based matrixes. Meanwhile, the crystallization of WC particles after heat treatment was more obvious than untreatment; the Ni matrix grain size was also grown remarkable, leading to the lower hardness and weaker plastic deformation resistance of Ni-65wt%WC coating. And the erosion results showed that the wear rate of coating gradually decreased with heat treatment temperature increasing, while brittle WC was not suitable for high impact wear conditions. Furthermore, with the increase of heat treatment temperature, the reciprocating wear performance showed that the friction coefficient and wear rate of Ni-65wt%WC coating decreased. And the friction coefficient and wear rate of the coating (700°C) in 3.5% NaCl solution were 0.15 and 4.82 × 10 mm·N·m, respectively. Therefore, the comprehensive comparison showed that Ni-65WC coating had better performance in low impact reciprocating testing under corrosion environment, and heat treatment was helpful to further improve the tribocorrosion performance of laser cladding Ni-65wt%WC coating.

摘要

采用激光熔覆技术在Q235表面制备了Ni-65wt%WC熔覆层,并研究了热处理对其微观结构和摩擦腐蚀性能的影响。结果表明,涂层主要由Ni、WC和WC组成,WC/Ni基体界面间形成了明显的扩散现象,有利于改善WC/Ni基金属间的结合层。同时,热处理后WC颗粒的结晶比未处理时更明显;Ni基体的晶粒尺寸也显著增大,导致Ni-65wt%WC涂层的硬度降低,抗塑性变形能力减弱。侵蚀结果表明,涂层的磨损率随热处理温度的升高而逐渐降低,而脆性的WC不适合高冲击磨损条件。此外,随着热处理温度的升高,往复磨损性能表明Ni-65wt%WC涂层的摩擦系数和磨损率降低。在3.5%NaCl溶液中,涂层(700°C)的摩擦系数和磨损率分别为0.15和4.82×10 mm·N·m。因此,综合比较表明,Ni-65WC涂层在腐蚀环境下的低冲击往复试验中具有较好的性能,热处理有助于进一步提高激光熔覆Ni-65wt%WC涂层的摩擦腐蚀性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4679/7455823/f192dfcb21d4/SCANNING2020-4843175.001.jpg

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