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戊烷泄漏引发爆炸的化学动力学研究

Study on Chemical Kinetics of Explosion Caused by Pentane Leakage.

作者信息

Meng Zhiqun, Wang Jinggang, Hou Liquan, Gao Ang, Qi Jiawen, Xiong Chuchao

机构信息

School of Energy and Environmental Engineering, Hebei University of Engineering, Handan 056038, PR China.

Hebei Zhong Tong Gas Equipment Science and Technology Company Limited, Handan 056038, PR China.

出版信息

ACS Omega. 2020 Aug 19;5(34):21669-21678. doi: 10.1021/acsomega.0c02510. eCollection 2020 Sep 1.

Abstract

Air-light hydrocarbon mixing gas with pentane as the main component is recognized as the "fourth urban gas" by the Chinese government. However, leakage may occur because of inadvertent human operation, and in this case, it is very easy to cause explosion. This paper mainly studies the changes in reactants, products, and free radicals during the explosion of pentane, especially the effects of oxygen and carbon monoxide concentrations on human body in this environment. In actual situations, excessive leakage of pentane is predominant. Once an explosion occurs, oxygen will be quickly consumed, and the concentration of carbon monoxide will rise abruptly. The high temperature resulting from the explosion can cause carbon dioxide to rarely react with carbon atoms to form carbon monoxide through the reaction of CO + C = 2CO. The research studies on the three major free radicals including hydrogen radical, oxygen radical, and hydroxyl radical are performed to provide theoretical support for preventing the chain reaction from further expanding the impact of explosion.

摘要

以戊烷为主要成分的轻质烃类混合气体被中国政府认定为“第四代城市燃气”。然而,由于人为操作疏忽可能会发生泄漏,在这种情况下极易引发爆炸。本文主要研究戊烷爆炸过程中反应物、产物及自由基的变化,特别是在此环境下氧气和一氧化碳浓度对人体的影响。在实际情况中,戊烷过量泄漏占主导。一旦发生爆炸,氧气会迅速消耗,一氧化碳浓度会急剧上升。爆炸产生的高温会使二氧化碳很少通过CO + C = 2CO反应与碳原子反应生成一氧化碳。对氢自由基、氧自由基和羟基自由基这三种主要自由基进行研究,为防止链式反应进一步扩大爆炸影响提供理论支持。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ecde/7469373/15cdb7d6c045/ao0c02510_0002.jpg

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