Li Xiangchun, Zhang Huan, Yang Chunli, Zhao Jianfei, Bai Sheng, Long Yuzhen
College of Emergency Management and Safety Engineering, China University of Mining and Technology, Beijing 100083, China.
State Key Laboratory of Coal Resources and Safe Mining, Beijing 100083, China.
ACS Omega. 2021 May 3;6(19):12513-12521. doi: 10.1021/acsomega.1c00153. eCollection 2021 May 18.
In order to explore the influence of water on the chain reaction characteristics of gas explosion, the 20 L explosion ball experiment and the homogeneous constant volume combustion reactor of CHEMKIN 17.0 simulations were carried out. The gas explosion response under four different water contents was tested and simulated. The effects of water on the pressure, free radicals, and reactants of gas explosion were compared and analyzed. The research results show that the inhibition of water on gas explosion was enhanced with the increase of water fraction in the initial mixture; the temperature, pressure, catastrophic gases such as CO, and concentration of activation centers in the reaction system can be reduced by water; the intensity of gas explosion can be reduced by inhibiting the formation of H, O, and OH free radicals, the main reactants of gas explosion and gas explosion energy.
为了探究水对气体爆炸链式反应特性的影响,开展了20L爆炸球实验以及CHEMKIN 17.0模拟的均相定容燃烧反应器实验。测试并模拟了四种不同含水量下的气体爆炸响应。比较并分析了水对气体爆炸压力、自由基和反应物的影响。研究结果表明,初始混合物中水分数增加时,水对气体爆炸的抑制作用增强;水可降低反应体系的温度、压力、诸如CO等灾难性气体以及活化中心浓度;通过抑制气体爆炸主要反应物H、O和OH自由基的形成以及气体爆炸能量,可降低气体爆炸强度。