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光诱导的胶束到囊泡转变以及光响应性孔雀石绿衍生物的包封

Photoinduced micelle-to-vesicle transition and encapsulation of by photoresponsive Malachite Green derivative.

作者信息

Uda Ryoko M, Tanabe Tomoyuki, Nakahara Yoshio, Kimura Keiichi

机构信息

Department of Chemical Engineering, Nara National College of Technology, Yata 22, Yamato-koriyama, Nara 639-1080, Japan.

Department of Applied Chemistry, Faculty of Systems Engineering, Wakayama University, Sakae-dani 930, Wakayama 640-8510, Japan.

出版信息

Soft Matter. 2008 Feb 21;4(3):560-563. doi: 10.1039/b716640k.

DOI:10.1039/b716640k
PMID:32907221
Abstract

UV irradiation on a Malachite Green leuconitrile derivative afforded a cationic surfactant in aqueous solutions of sodium bis(2-ethylhexyl) sulfosuccinate. The result involved a micelle-to-vesicle transition and encapsulation which have been investigated by trapping experiment. Transmission electron microscopy was applied for direct observation of vesicle formation. The micellar solution was studied under dark conditions with pyrene emission spectra.

摘要

在双(2-乙基己基)磺基琥珀酸钠水溶液中,对孔雀石绿亚硝腈衍生物进行紫外线照射可得到一种阳离子表面活性剂。该结果涉及胶束到囊泡的转变和包封,已通过捕获实验进行了研究。应用透射电子显微镜直接观察囊泡的形成。在黑暗条件下,利用芘发射光谱对胶束溶液进行了研究。

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