Ojaghi Aghbash Khadijeh, Noroozi Pesyan Nader, Batmani Hana
Department of Organic Chemistry, Faculty of Chemistry, Urmia University, Urmia 57159, Iran.
ACS Omega. 2020 Aug 27;5(35):22099-22108. doi: 10.1021/acsomega.0c02115. eCollection 2020 Sep 8.
Cu-Kojic acid (KA) complex anchored to functionalized silica-MCM-41 was synthesized via the process of postgrafting and introduced as an effective, new, reusable, and thermally resistant heterogeneous nanocatalyst for the clean synthesis of 1-1,2,3-triazoles from Click reaction of 2-(azidomethyl)-5-benzyloxy-4-pyrone and azido Kojic acid with a variety of terminal alkynes in excellent yields. The structure of nanocatalyst was analyzed by ICP, BET, XRD, EDS, SEM, TGA, TEM, and FT-IR techniques.
通过后接枝法合成了负载于功能化二氧化硅-MCM-41上的铜-曲酸(KA)配合物,并将其作为一种有效、新型、可重复使用且耐热的多相纳米催化剂,用于通过2-(叠氮甲基)-5-苄氧基-4-吡喃酮与叠氮曲酸与多种末端炔烃的点击反应,以优异的产率清洁合成1,2,3-三唑。通过电感耦合等离子体质谱(ICP)、比表面积分析仪(BET)、X射线衍射仪(XRD)、能谱仪(EDS)、扫描电子显微镜(SEM)、热重分析仪(TGA)、透射电子显微镜(TEM)和傅里叶变换红外光谱仪(FT-IR)技术对纳米催化剂的结构进行了分析。