评论“Zr(iv) 和 Zr(iv) 与羟肟酸的络合研究：设计比去铁胺 B 更好的螯合剂用于免疫 PET 成像的进展”，F. Guérard、Y.-S. Lee、R. Tripier、L. P. Szajek、J. R. Deschamps 和 M. W. Brechbiel，Chem. Commun.，2013，49，1002。
Comment on "Investigation of Zr(iv) and Zr(iv) complexation with hydroxamates: progress towards designing a better chelator than desferrioxamine B for immuno-PET imaging" by F. Guérard, Y.-S. Lee, R. Tripier, L. P. Szajek, J. R. Deschamps and M. W. Brechbiel, Chem. Commun., 2013, 49, 1002.
机构信息
Department of Chemistry "Ugo Schiff", University of Florence, Italy.
出版信息
Chem Commun (Camb). 2020 Oct 25;56(83):12664-12666. doi: 10.1039/d0cc01189d. Epub 2020 Sep 18.
PMID:32944720
Abstract
An alternative analysis of the complexes formed by Zr(iv) with acetohydroxamate shows that, in comparison with the results reported in the title article, a more complicated complexation model is found, the stability constants of the common complexes are considerably different and complexation of Zr(iv) does not show any unusual behaviour.
摘要
Zr(iv) 与乙酰羟肟酸形成的配合物的另一种分析表明，与标题文章中报道的结果相比，发现了一个更复杂的配合物模型，常见配合物的稳定常数有很大的不同，Zr(iv) 的配合物没有表现出任何异常行为。
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