{VMoO[RC(CHO)]}：第一类三醇配体共价修饰的Keggin型多氧钼酸盐。
{VMoO[RC(CHO)]}: the first class of triol ligand covalently-decorated Keggin-type polyoxomolybdates.
作者信息
Qu Di, Liu Xiaoting, Duan Fengxue, Xue Rong, Li Bao, Wu Lixin
机构信息
State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, P. R. China.
出版信息
Dalton Trans. 2020 Oct 7;49(37):12950-12954. doi: 10.1039/d0dt02506b. Epub 2020 Sep 21.
PMID:32955045
Abstract
Three trivacant polyoxomolybdates were constructed, presenting the first class of triol ligand covalently-decorated Keggin-type clusters through C-O-Mo bonds. The introduction of the organic component enhanced the stability of the cluster in the solid state with the leaving of active sites at the lacunary position.
摘要
构建了三种三缺位多氧钼酸盐，它们是通过C-O-Mo键共价修饰的第一类三醇配体的Keggin型簇合物。有机成分的引入增强了簇合物在固态下的稳定性，同时在缺位位置留下了活性位点。
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