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亚马孙克拉通东南部卡拉雅斯矿产省土壤中潜在有毒元素的地球化学背景浓度。

Geochemical background concentrations of potentially toxic elements in soils of the Carajás Mineral Province, southeast of the Amazonian Craton.

作者信息

de Lima Mauricio Wilians, Hamid Sheryle Santos, de Souza Edna Santos, Teixeira Renato Alves, da Conceição Palheta Dulcidéia, do Carmo Freitas Faial Kelson, Fernandes Antonio Rodrigues

机构信息

Institute of Agricultural Sciences, Federal Rural University of Amazon, (ICA-UFRA), C. P. 917, Belém, PA, 66077-530, Brazil.

Institute of Studies on Xingu, Federal University of Southern and Southeastern Pará, R. Constantino Viana Street, S/N, São Felix do Xingu, PA, 68380-000, Brazil.

出版信息

Environ Monit Assess. 2020 Sep 21;192(10):649. doi: 10.1007/s10661-020-08611-9.

Abstract

The objective of this study was to establish background concentrations of potentially toxic elements (PTEs) in soils from the Carajás Mineral Province (CMP), southeastern Amazonian Craton. The PTEs Al, Ba, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, Ti, V, and Zn were digested in microwaves and quantified by optical emission spectrometry (ICP OES). The variability of physical-chemical and mineralogical attributes contributed to variation in PTE concentrations. High background concentrations of Al, Fe, Cr, Mn, Mo, Ni, Ti, and V and, in particular, the PTE concentrations of Cd, Cu, Cr, Ba, and Co were greater than the prevention values defined by the Brazilian National Council of Environment. Soil quality reference values (QRVs) were greater than those determined for most Brazilian states and soils in the state of Pará. The high background concentrations and QRVs of PTEs show that the region is strongly influenced by the source material, rich in ferruginous deposits and other associated minerals. The results are an important tool for establishing soil quality standards and public policies for environmental protection in regions naturally PTE enriched.

摘要

本研究的目的是确定亚马孙克拉通东南部卡拉雅斯矿产省(CMP)土壤中潜在有毒元素(PTEs)的背景浓度。采用微波消解PTEs铝、钡、镉、钴、铬、铜、铁、锰、镍、铅、钛、钒和锌,并通过光发射光谱法(ICP OES)进行定量分析。物理化学和矿物学属性的变异性导致了PTEs浓度的变化。铝、铁、铬、锰、钼、镍、钛和钒的背景浓度较高,特别是镉、铜、铬、钡和钴的PTEs浓度高于巴西国家环境委员会规定的预防值。土壤质量参考值(QRVs)高于巴西大多数州以及帕拉州土壤的测定值。PTEs的高背景浓度和QRVs表明,该地区受富含铁沉积物和其他相关矿物的源材料影响很大。研究结果是在自然富含PTEs的地区建立土壤质量标准和环境保护公共政策的重要工具。

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