表面固定化二亚胺铜（I）光敏剂作为用于阐明界面处受限效应以实现太阳能转换的分子探针。
Surface immobilized copper(I) diimine photosensitizers as molecular probes for elucidating the effects of confinement at interfaces for solar energy conversion.
作者信息
Eberhart Michael S, Phelan Brian T, Niklas Jens, Sprague-Klein Emily A, Kaphan David M, Gosztola David J, Chen Lin X, Tiede David M, Poluektov Oleg G, Mulfort Karen L
机构信息
Division of Chemical Sciences and Engineering, Argonne National Laboratory, Lemont, IL 60439, USA.
Center for Nanoscale Materials, Argonne National Laboratory, Lemont, IL 60439, USA.
出版信息
Chem Commun (Camb). 2020 Oct 13;56(81):12130-12133. doi: 10.1039/d0cc05972b.
Heteroleptic copper(i) bis(phenanthroline) complexes with surface anchoring carboxylate groups have been synthesized and immobilized on nanoporous metal oxide substrates. The species investigated are responsive to the external environment and this work provides a new strategy to control charge transfer processes for efficient solar energy conversion.
已合成了带有表面锚定羧基的异质双（菲咯啉）铜（I）配合物，并将其固定在纳米多孔金属氧化物基底上。所研究的物质对外部环境有响应，这项工作为控制电荷转移过程以实现高效太阳能转换提供了一种新策略。
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