共价有机框架——超越分子的有机化学
Covalent Organic Frameworks-Organic Chemistry Beyond the Molecule.
作者信息
Diercks Christian S, Kalmutzki Markus J, Yaghi Omar M
机构信息
Department of Chemistry, University of California, Berkeley, CA 94720, USA.
Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA.
出版信息
Molecules. 2017 Sep 19;22(9):1575. doi: 10.3390/molecules22091575.
The synthesis of organic molecules has at its core, purity, definitiveness of structure, and the ability to access specific atoms through chemical reactions. When considering extended organic structures, covalent organic frameworks (COFs) stand out as a true extension of molecular organic chemistry to the solid state, because these three fundamental attributes of molecular organic chemistry are preserved. The fact that COFs are porous provides confined space within which molecules can be further modified and controlled.
有机分子的合成其核心在于纯度、结构的确定性以及通过化学反应获取特定原子的能力。在考虑扩展有机结构时，共价有机框架（COFs）作为分子有机化学向固态的真正延伸脱颖而出，因为分子有机化学的这三个基本属性得以保留。COFs具有多孔性这一事实提供了受限空间，分子可在其中进一步修饰和控制。
Zotero 插件