H Detection Using Plasmonically Generated Surface Photoacoustic Waves in Pd Nanoparticle-Deposited GaN Microcantilevers.

Detection of H using plasmonic amplification of surface photoacoustic (SPA) waves generated in Pd nanoparticle-deposited GaN piezotransistive microcantilevers has been investigated using a pulsed 520 nm laser. Using 1.5 nm thickness of the Pd functionalization layer, H detection down to 1.5 ppm was demonstrated with a high signal-to-noise ratio, underscoring the feasibility of sub-ppm level detection using this novel sensing method. Adsorption of H in Pd nanoparticles (NPs) changes their plasmonic absorption spectra because of Pd lattice expansion, in addition to changing their work function. The high sensitivity exhibited by the SPA-based H detection method is attributed to a combination of changes in the plasmonic spectrum and work function of Pd NPs and was observed to be a strong function of Pd thickness, biasing conditions, and probe laser power. A comparison of the SPA-based detection technique with traditional chemidiode and chemiresistor sensors, integrated in the functionalized piezotransistor, indicated a superior detection performance of the former.