Flamini Guido, Najar Basma, Leonardi Michele, Ambryszewska Katarzyna E, Cioni Pier Luigi, Parri Federico, Melai Bernardo, Pistelli Luisa
Dipartimento di Farmacia, Università di Pisa, Pisa, Italy.
Centro Interdipartimentale di Ricerca Nutraceutica e Alimentazione per la Salute "Nutrafood", Università di Pisa, Pisa, Italy.
Nat Prod Res. 2022 Apr;36(7):1919-1925. doi: 10.1080/14786419.2020.1824229. Epub 2020 Sep 25.
The hydrodistilled essential oils from eighteen samples of Spenn. collected in six localities of Elba Island (Tuscany, Italy) during three different seasonal periods were analyzed by GC-MS for the first time. Fifty-five components were identified, representing 96.8-99.6% of the total chemical composition. All the tested essential oils were characterized by a high content of monoterpenes (oxygenated 49.2-80.3%; hydrocarbons 18.7-48.3%). Among them, 1,8-cineole (26.4-49.1%), α-pinene (4.5-34.8%), camphor (1.1-18.8%) and borneol (1.7-16.2%) were the main constituents. The high amount of 1,8-cineole/α-pinene/camphor/borneol may suggest the presence of an intermediate rosemary chemotype. Statistical analysis was also performed on the essential oil (EO) composition evidenced an expected difference depending on the collection seasons, to the geographical areas and soil composition. A comparison with the essential oil composition from collected in all the other islands of Tuscan Archipelago (Italy) was also reported, together with a Multivariate Statistical Analysis.
首次采用气相色谱 - 质谱联用仪(GC - MS)分析了在意大利托斯卡纳厄尔巴岛六个地点采集的18个迷迭香(Rosmarinus officinalis L.)样本在三个不同季节经水蒸馏得到的挥发油。共鉴定出55种成分,占化学成分总量的96.8 - 99.6%。所有测试挥发油的特征均为单萜含量高(氧化单萜49.2 - 80.3%;烃类18.7 - 48.3%)。其中,1,8 - 桉叶素(26.4 - 49.1%)、α - 蒎烯(4.5 - 34.8%)、樟脑(1.1 - 18.8%)和冰片(1.7 - 16.2%)是主要成分。1,8 - 桉叶素/α - 蒎烯/樟脑/冰片含量高可能表明存在中间型迷迭香化学型。还对挥发油(EO)成分进行了统计分析,结果表明根据采集季节、地理区域和土壤成分存在预期差异。此外,还报告了与在意大利托斯卡纳群岛所有其他岛屿采集的迷迭香挥发油成分的比较以及多元统计分析结果。