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高级产甲烷性能和高固体厌氧膜生物反应器(AnMBR)用于食物垃圾和污水污泥共消化的结垢机制研究。

Advanced methanogenic performance and fouling mechanism investigation of a high-solid anaerobic membrane bioreactor (AnMBR) for the co-digestion of food waste and sewage sludge.

机构信息

Department of Civil and Environmental Engineering, Graduate School of Engineering, Tohoku University, 6-6-06 Aoba, Aramaki-Aza, Sendai, Miyagi 980-8579, Japan.

Department of Frontier Science for Advanced Environment, Graduate School of Environmental Studies, Tohoku University, 6-6-20 Aoba, Aramaki-Aza, Sendai, Miyagi 980-8579, Japan.

出版信息

Water Res. 2020 Dec 15;187:116436. doi: 10.1016/j.watres.2020.116436. Epub 2020 Sep 18.

Abstract

Disposal of the increasingly huge amounts of sewage sludge (SeS) has become an impending problem worldwide. To solve this problem, a high-solid anaerobic membrane bioreactor (AnMBR) was used for the anaerobic co-digestion (AcoD) of SeS and food waste (FW). This study investigated the effects of SeS ratio on the methanogenic performance of the AcoD with a gradual increase value from 0 to 25%, 50%, 75% and 100% (total solids based). The results showed that the highest methanogenic performance was achieved at mono FW digestion. As for the co-digestion, the optimal FW/SeS ratio for methanogenic performance was 75%:25% among all the mixing ratios. The COD based biogas yield and methane yield were 0.498 L-biogas/g-COD and 0.295 L-CH/g-COD at this optimal mixing ratio, which were 67.7% and 67.6% higher than those of the mono SeS digestion, respectively. The upgraded values were attributed to the improved hydrolysis ratio (by 8.14%) and the balanced carbon-to-nitrogen (C/N) ratio by co-digestion with FW, which synergistically stimulated methanogenesis ratio by 81.0%. The continuous membrane filtration property was investigated and four typical trans-membrane pressure (TMP) variation curves at different fouling degrees were determined. The membrane could sustainably operate at a flux of 6 L/m/h (LMH) at the mixed liquor total solids (MLTS) concentration of 25 - 30 g/L. The combination of continuous membrane filtration property, particle size distribution of the mixed liquor and the external forces analysis was firstly applied to unravel the membrane fouling mechanism of a high-solid AnMBR. The result of this study will contribute to the establishment of an efficient FW and SeS treatment strategy.

摘要

处理日益增多的污水污泥 (SeS) 已成为全球迫在眉睫的问题。为了解决这个问题,采用高固体厌氧膜生物反应器 (AnMBR) 对 SeS 和食物废物 (FW) 进行厌氧共消化 (AcoD)。本研究通过逐步增加 SeS 比例(基于总固体),从 0%、25%、50%、75%到 100%,考察了 SeS 比例对 AcoD 产甲烷性能的影响。结果表明,单独 FW 消化时产甲烷性能最高。对于共消化,所有混合比例中,FW/SeS 比例为 75%:25%时产甲烷性能最佳。在最佳混合比例下,基于 COD 的沼气产率和甲烷产率分别为 0.498 L-沼气/g-COD 和 0.295 L-CH/g-COD,分别比单独 SeS 消化高 67.7%和 67.6%。这归因于水解比(提高了 8.14%)和 FW 共消化带来的平衡碳氮比(C/N),这协同刺激了产甲烷比提高 81.0%。还考察了连续膜过滤性能,并确定了不同污染程度下的四个典型跨膜压力 (TMP) 变化曲线。在混合液总固体 (MLTS) 浓度为 25-30 g/L 的条件下,膜可在 6 L/m/h (LMH) 的通量下持续运行。首次将连续膜过滤性能、混合液颗粒尺寸分布和外力分析相结合,揭示了高固体 AnMBR 的膜污染机制。本研究结果将有助于建立有效的 FW 和 SeS 处理策略。

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