Institute of Chemistry, University of the Punjab, New Campus, Lahore, Pakistan.
Interdisciplinary Research Centre in Biomedical Materials, COMSATS University Islamabad, Lahore Campus, Lahore, Pakistan.
Crit Rev Anal Chem. 2022;52(4):756-767. doi: 10.1080/10408347.2020.1824117. Epub 2020 Sep 27.
Development of economical, sensitive, selective and robust sensors for metal ion sensing is always fascinating for a chemist because traditional routs for their detection involve complicated instrumentation and critical sample preparation procedures. A large number of metal ion detectors including carbon dots (CDs) have been reported for sensitive and selective detection of metal ions. This review comprehensively explores the use of CDs as metallic cation sensors. CDs are being fabricated from variety of carbon sources by employing various synthetic channels. CDs are proved to be efficient colorimetric and fluorimetric detectors due to surface oxygen moieties which are responsible to co-ordinate with metal ions. Doping of CDs with hetero atom such as N, S, B etc. may further enhance their activity toward metal detection. Therefore, designing of CDs having selective sensing properties with low detection limits has gained significant interest.HighlightsCDs have gained much attention as chemical sensors due to their dynamic features i.e. less toxicity, stability, solubility in various solvents, absorption in UV/Vis. region, fluorescence and tunable physico-chemical properties.These are coast effective, sensitive and selective colorimetric and fluorimetric metal ion sensors.Detection of metal ions by CDs involves different mechanisms such as complexation, aggregation, electron transfer, inner filter effect etc.LOD data is an evidence of their greater efficiency.
开发用于金属离子传感的经济、灵敏、选择性和稳健传感器一直令化学家着迷,因为传统的金属离子检测方法涉及复杂的仪器和关键的样品制备程序。已经有大量的金属离子探测器,包括碳点 (CDs),被报道用于金属离子的灵敏和选择性检测。本综述全面探讨了 CDs 作为金属阳离子传感器的应用。通过采用各种合成途径,从各种碳源制备 CDs。由于表面氧基团与金属离子配位,CDs 被证明是有效的比色和荧光探测器。通过掺杂杂原子,如 N、S、B 等,进一步提高了它们对金属检测的活性。因此,设计具有低检测限的选择性传感特性的 CDs 引起了人们的极大兴趣。
CDs 因其动态特性,如低毒性、稳定性、在各种溶剂中的溶解度、在 UV/Vis 区域的吸收、荧光和可调的物理化学性质,作为化学传感器引起了广泛关注。
CDs 是具有成本效益、灵敏和选择性的比色和荧光金属离子传感器。
CDs 检测金属离子涉及不同的机制,如络合、聚集、电子转移、内滤效应等。
LOD 数据证明了它们的更高效率。