Hou Chuang, Tai Guoan, Wu Zenghui, Hao Jinqian
The State Key Laboratory of Mechanics and Control of Mechanical Structures, Laboratory of Intelligent Nano Materials and Devices of Ministry of Education, College of Aerospace Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing, 210016, P. R. China.
Chempluschem. 2020 Sep;85(9):2186-2196. doi: 10.1002/cplu.202000550.
Borophenes (2D boron sheets) have triggered a surge of interest both theoretically and experimentally because of its distinct structural, optical and electronic properties for extensive potential applications. Although theoretical efforts have guided the research directions of borophene, only few synthetic borophene sheets have been demonstrated experimentally. Borophene sheets have been successfully synthesized experimentally on metal substrates until 2015. Afterwards, more efforts were put on the controlled synthesis of crystalline and semiconducting borophene sheets as well as on the investigation of their novel and fascinating physical properties. This report provides a brief review on theoretical and experimental progress in borophene research. Some typical structures and properties of borophenes have been reviewed. The focus is laid on summarizing the experimental synthesis of borophene in recent years, and on showing some ultrastable and semiconducting borophenes which have been applied in electronic information devices. Finally, the future challenges and opportunities regarding experimental realization and practical applications of borophenes are presented.
硼烯(二维硼片)因其独特的结构、光学和电子特性在广泛的潜在应用中展现出巨大潜力,在理论和实验方面均引发了广泛关注。尽管理论研究为硼烯的研究方向提供了指导,但仅有少数合成硼烯片在实验中得到证实。直到2015年,硼烯片才在金属衬底上成功地通过实验合成。此后,更多的研究工作集中在可控合成晶体和半导体硼烯片以及对其新颖迷人的物理性质的研究上。本报告简要回顾了硼烯研究在理论和实验方面的进展。文中对硼烯的一些典型结构和性质进行了综述。重点在于总结近年来硼烯的实验合成方法,并展示一些已应用于电子信息器件的超稳定和半导体硼烯。最后,还介绍了硼烯在实验实现和实际应用方面未来面临的挑战与机遇。